Zigzag octahedral cluster chains in BaMo6O10

K. H. Lii, C. C. Wang, S. L. Wang

研究成果: 雜誌貢獻期刊論文同行評審

26 引文 斯高帕斯(Scopus)

摘要

A novel ternary molybdenum oxide, BaMo6O10, was discovered and its crystal structure was determined from single-crystal X-ray diffraction data. BaMo6O10 crystallizes in the orthorhombic space group Pnma with a = 10.154(2), b = 8.641(2), c = 9.184(2)Å, V = 805.7(3)Å3, Z = 4, R = 0.0438, Rw = 0.0401 for 652 independent reflections with I > 3.0σ(I). The structure contains infinite zigzag molybdenum oxide chains built up from M6X12-type clusters, crosslinked to form channels where Ba2+ cations reside. Bond distance analysis results indicate that BaMo6O10 is perfectly bonded with all valence electrons of the Mo atoms in either MoMo or MoO bonding states.

原文???core.languages.en_GB???
頁(從 - 到)407-411
頁數5
期刊Journal of Solid State Chemistry
77
發行號2
DOIs
出版狀態已出版 - 12月 1988

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