TY - JOUR
T1 - Zigzag octahedral cluster chains in BaMo6O10
AU - Lii, K. H.
AU - Wang, C. C.
AU - Wang, S. L.
N1 - Funding Information:
Support for this study by the National Science Council and the Institute of Chemistry Academia Sinica are gratefully acknowledged.
PY - 1988/12
Y1 - 1988/12
N2 - A novel ternary molybdenum oxide, BaMo6O10, was discovered and its crystal structure was determined from single-crystal X-ray diffraction data. BaMo6O10 crystallizes in the orthorhombic space group Pnma with a = 10.154(2), b = 8.641(2), c = 9.184(2)Å, V = 805.7(3)Å3, Z = 4, R = 0.0438, Rw = 0.0401 for 652 independent reflections with I > 3.0σ(I). The structure contains infinite zigzag molybdenum oxide chains built up from M6X12-type clusters, crosslinked to form channels where Ba2+ cations reside. Bond distance analysis results indicate that BaMo6O10 is perfectly bonded with all valence electrons of the Mo atoms in either MoMo or MoO bonding states.
AB - A novel ternary molybdenum oxide, BaMo6O10, was discovered and its crystal structure was determined from single-crystal X-ray diffraction data. BaMo6O10 crystallizes in the orthorhombic space group Pnma with a = 10.154(2), b = 8.641(2), c = 9.184(2)Å, V = 805.7(3)Å3, Z = 4, R = 0.0438, Rw = 0.0401 for 652 independent reflections with I > 3.0σ(I). The structure contains infinite zigzag molybdenum oxide chains built up from M6X12-type clusters, crosslinked to form channels where Ba2+ cations reside. Bond distance analysis results indicate that BaMo6O10 is perfectly bonded with all valence electrons of the Mo atoms in either MoMo or MoO bonding states.
UR - http://www.scopus.com/inward/record.url?scp=0024132147&partnerID=8YFLogxK
U2 - 10.1016/0022-4596(88)90265-4
DO - 10.1016/0022-4596(88)90265-4
M3 - 期刊論文
AN - SCOPUS:0024132147
VL - 77
SP - 407
EP - 411
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 2
ER -