Water splitting reaction on NiO/InVO4 under visible light irradiation

Hsin Yu Lin, Yueh Fang Chen, Yu Wen Chen

研究成果: 雜誌貢獻期刊論文同行評審

104 引文 斯高帕斯(Scopus)

摘要

The photocatalytic activities of InVO4 and NiO/InVO4 for water splitting under visible light irradiation were investigated. NiO/InVO4 photocatalysts pretreated by different process were also investigated. The catalysts were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and UV-vis spectroscopy. The photocatalytic reaction was carried out in a Pyrex glass reactor under visible light irradiation. The XRD patterns indicated that the InVO4 material was fully crystallized. SEM images showed that after loading NiO, many pin-holes were observed on the surface of the InVO4 particles. The particle size of the catalyst was about 5 μ m. The band gap of InVO4 samples was 1.8 eV as estimated from UV-vis spectra. InVO4 was very active to produce H2. The NiO/InVO4 catalyst which was reduced at 500 {ring operator} C for 2 h and then oxidized at ambient condition for 48 h gave the highest activity, which demonstrated that the pre-treatment process plays a key role in creating high catalytic performance for the NiO/InVO4 catalyst.

原文???core.languages.en_GB???
頁(從 - 到)86-92
頁數7
期刊International Journal of Hydrogen Energy
32
發行號1
DOIs
出版狀態已出版 - 1月 2007

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