UF3(H2O)(C2O4)0.5: A fluorooxalate of tetravalent uranium with a three-dimensional framework structure

Chih Min Wang; Chia Hsien Liao; Pei Lin Chen; Kwang Hwa Lii

doi:10.1021/ic051960v

UF₃(H₂O)(C₂O₄)_0.5: A fluorooxalate of tetravalent uranium with a three-dimensional framework structure

Chih Min Wang, Chia Hsien Liao, Pei Lin Chen, Kwang Hwa Lii

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

14 引文斯高帕斯（Scopus）

摘要

A new uranium(IV) fluorooxalate, UF₃(H₂O)(C ₂O₄)_0.5, has been synthesized by a hydrothermal method and structurally characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of two-dimensional layers of corner- and edge-sharing tricapped trigonal prisms with the composition UF4_/2F_2/2O₃ linked by bisbidentate oxalate ligands to form a three-dimensional framework. Magnetic susceptibilities were measured to confirm the tetravalent state of uranium. Crystal data: monoclinic, space group C2/c₁ a = 17.246(3) Å, b = 6.088(1) Å, c = 8.589(2) Å, β = 95.43(3)°, and Z = 8.

原文	???core.languages.en_GB???
頁（從 - 到）	1436-1438
頁數	3
期刊	Inorganic Chemistry
卷	45
發行號	4
DOIs	https://doi.org/10.1021/ic051960v
出版狀態	已出版 - 20 2月 2006

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10.1021/ic051960v

CCDC 600266: Experimental Crystal Structure Determination
Wang, C.-M. (???dataset.roles.dataset.creator???), Liao, C.-H. (???dataset.roles.dataset.creator???), Chen, P.-L. (???dataset.roles.dataset.creator???) & Lii, K.-H. (???dataset.roles.dataset.creator???), The Cambridge Structural Database, 2006
DOI: 10.5517/ccn4mft, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccn4mft&sid=DataCite
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title = "UF3(H2O)(C2O4)0.5: A fluorooxalate of tetravalent uranium with a three-dimensional framework structure",

abstract = "A new uranium(IV) fluorooxalate, UF3(H2O)(C 2O4)0.5, has been synthesized by a hydrothermal method and structurally characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of two-dimensional layers of corner- and edge-sharing tricapped trigonal prisms with the composition UF4/2F2/2O3 linked by bisbidentate oxalate ligands to form a three-dimensional framework. Magnetic susceptibilities were measured to confirm the tetravalent state of uranium. Crystal data: monoclinic, space group C2/c1 a = 17.246(3) {\AA}, b = 6.088(1) {\AA}, c = 8.589(2) {\AA}, β = 95.43(3)°, and Z = 8.",

author = "Wang, {Chih Min} and Liao, {Chia Hsien} and Chen, {Pei Lin} and Lii, {Kwang Hwa}",

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T2 - A fluorooxalate of tetravalent uranium with a three-dimensional framework structure

AU - Wang, Chih Min

AU - Liao, Chia Hsien

AU - Chen, Pei Lin

AU - Lii, Kwang Hwa

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N2 - A new uranium(IV) fluorooxalate, UF3(H2O)(C 2O4)0.5, has been synthesized by a hydrothermal method and structurally characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of two-dimensional layers of corner- and edge-sharing tricapped trigonal prisms with the composition UF4/2F2/2O3 linked by bisbidentate oxalate ligands to form a three-dimensional framework. Magnetic susceptibilities were measured to confirm the tetravalent state of uranium. Crystal data: monoclinic, space group C2/c1 a = 17.246(3) Å, b = 6.088(1) Å, c = 8.589(2) Å, β = 95.43(3)°, and Z = 8.

AB - A new uranium(IV) fluorooxalate, UF3(H2O)(C 2O4)0.5, has been synthesized by a hydrothermal method and structurally characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of two-dimensional layers of corner- and edge-sharing tricapped trigonal prisms with the composition UF4/2F2/2O3 linked by bisbidentate oxalate ligands to form a three-dimensional framework. Magnetic susceptibilities were measured to confirm the tetravalent state of uranium. Crystal data: monoclinic, space group C2/c1 a = 17.246(3) Å, b = 6.088(1) Å, c = 8.589(2) Å, β = 95.43(3)°, and Z = 8.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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UF3(H2O)(C2O4)0.5: A fluorooxalate of tetravalent uranium with a three-dimensional framework structure

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指紋

資料集

CCDC 600266: Experimental Crystal Structure Determination

引用此

UF₃(H₂O)(C₂O₄)_0.5: A fluorooxalate of tetravalent uranium with a three-dimensional framework structure