Transient frequency modulation spectroscopy and 266 nm photodissociation of bromoform

Wen Ling Liu, Bor Chen Chang

研究成果: 雜誌貢獻期刊論文同行評審

15 引文 斯高帕斯(Scopus)

摘要

A high-resolution absorption spectrometer, based on the combination of frequency-modulation (FM) and diode laser techniques, has been constructed to investigate the reaction intermediates in the 266 nm laser photolysis of bromoform (CHBr3). The absorption spectrum of HCBr corresponding to the Ã1A″ ← X̃1A′ electronic transition was successfully obtained. We also found that the nascent HCBr is electronically excited. These data indicate that in the reaction pathway we observed, the first step of the 266 nm photolysis is a two-photon process and HCBr is one of the primary intermediates. The electronically excited HCBr absorbs one or two more photons to produce the electronically excited CH radical.

原文???core.languages.en_GB???
頁(從 - 到)613-617
頁數5
期刊Journal of the Chinese Chemical Society
48
發行號3
DOIs
出版狀態已出版 - 2001

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