Toward environmentally compatible molecular solar cells processed from halogen-free solvents

Mahmoud E. Farahat, Cheng Si Tsao, Yu Ching Huang, Sheng Hsiung Chang, Widhya Budiawan, Chun Guey Wu, Chih Wei Chu

研究成果: 雜誌貢獻期刊論文同行評審

23 引文 斯高帕斯(Scopus)

摘要

Replacing toxic halogenated solvents with eco-friendly solvents will be necessary for the upscaling and mass production of organic photovoltaics (OPVs). In this study, toluene (Tol), a halogen-free solvent, was employed in the fabrication of molecular solar cells, achieving a power conversion efficiency (PCE) higher than that obtained when using a chlorinated counterpart, chloroform (CF). SMPV1, a two-dimensional conjugated small molecule, was used as the donor and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM) as the acceptor to form bulk heterojunction (BHJ) OPVs. The as-cast device formed using Tol displayed a PCE of 5.4%, higher than that (4.8%) achieved using CF. Combining the effects of thermal annealing and polydimethylsiloxane (PDMS) as a solvent additive, the PCEs of devices prepared using Tol and CF reached 6.20 and 5.52%, respectively. Solvent vapor annealing (SVA), a powerful tool for controlling the morphology of the active layer, had a great impact on the device performance. Tol, tetrahydrofuran (THF), carbon disulphide (CS2), and hexane (Hex) were tested as halogen-free solvents for SVA treatment. Tol- and THF-SVA had positive effects on PCEs, reaching 7.04 and 6.50%, respectively. The enhancement arose mainly from the improvement in the fill factor, due to morphological manipulation and favorable phase separation. CS2- and Hex-SVA treatment had negative effects on the short-circuit current density and, hence, the overall PCE. A PCE of greater than 7% is the highest performance reported to date when using a halogen-free solvent to prepare small-molecule solar cells.

原文???core.languages.en_GB???
頁(從 - 到)7341-7351
頁數11
期刊Journal of Materials Chemistry A
4
發行號19
DOIs
出版狀態已出版 - 2016

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