Thin film trichloroethylene electrochemical sensor

Min Hua Chen; Chung Chiun Liu; Tse Chuan Chou

doi:10.1016/j.bios.2004.01.017

Thin film trichloroethylene electrochemical sensor

Min Hua Chen, Chung Chiun Liu, Tse Chuan Chou

材料科學與工程研究所

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

7 引文斯高帕斯（Scopus）

摘要

Pt-Ti and Pb-Pt-Ti thin films were deposited on alumina substrates by sputtering in Ar gas. In this study, an electrodeposited Pb-modified Pt-Ti thin film working electrode was prepared. Optimal sensing conditions were found to be -2.10 V (versus Ag/Ag⁺ with 0.1 M tetrabutylammonium perchlorate (TBAP) in acetonitrile (AN) solution) sensing potential, 250 rpm agitation rate. At room temperature, the response time was 15 s (90% response time). The correlation of sensing response current, i_d, and trichloroethylene (TCE) concentration, C_L, is i_d=2.86C_L in the range from 100 to 700 ppm TCE. Additionally, the rate constant of (TCE) cathodic reduction was found to be 2.434×10^-3 cm^-1 s ^-1.

原文	???core.languages.en_GB???
頁（從 - 到）	25-32
頁數	8
期刊	Biosensors and Bioelectronics
卷	20
發行號	1
DOIs	https://doi.org/10.1016/j.bios.2004.01.017
出版狀態	已出版 - 30 7月 2004

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10.1016/j.bios.2004.01.017

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title = "Thin film trichloroethylene electrochemical sensor",

abstract = "Pt-Ti and Pb-Pt-Ti thin films were deposited on alumina substrates by sputtering in Ar gas. In this study, an electrodeposited Pb-modified Pt-Ti thin film working electrode was prepared. Optimal sensing conditions were found to be -2.10 V (versus Ag/Ag+ with 0.1 M tetrabutylammonium perchlorate (TBAP) in acetonitrile (AN) solution) sensing potential, 250 rpm agitation rate. At room temperature, the response time was 15 s (90% response time). The correlation of sensing response current, id, and trichloroethylene (TCE) concentration, CL, is id=2.86CL in the range from 100 to 700 ppm TCE. Additionally, the rate constant of (TCE) cathodic reduction was found to be 2.434×10-3 cm-1 s -1.",

keywords = "Electrodeposited Pb-modified Pt-Ti thin film, Sensor, Trichloroethylene",

author = "Chen, {Min Hua} and Liu, {Chung Chiun} and Chou, {Tse Chuan}",

note = "Funding Information: The support of the Ministry of Education of Republic of China (EX-91-E-FA09-5-4), National Cheng Kung University and Case Western Reserve University are gratefully acknowledgment. ",

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doi = "10.1016/j.bios.2004.01.017",

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T1 - Thin film trichloroethylene electrochemical sensor

AU - Chen, Min Hua

AU - Liu, Chung Chiun

AU - Chou, Tse Chuan

N1 - Funding Information: The support of the Ministry of Education of Republic of China (EX-91-E-FA09-5-4), National Cheng Kung University and Case Western Reserve University are gratefully acknowledgment.

PY - 2004/7/30

Y1 - 2004/7/30

N2 - Pt-Ti and Pb-Pt-Ti thin films were deposited on alumina substrates by sputtering in Ar gas. In this study, an electrodeposited Pb-modified Pt-Ti thin film working electrode was prepared. Optimal sensing conditions were found to be -2.10 V (versus Ag/Ag+ with 0.1 M tetrabutylammonium perchlorate (TBAP) in acetonitrile (AN) solution) sensing potential, 250 rpm agitation rate. At room temperature, the response time was 15 s (90% response time). The correlation of sensing response current, id, and trichloroethylene (TCE) concentration, CL, is id=2.86CL in the range from 100 to 700 ppm TCE. Additionally, the rate constant of (TCE) cathodic reduction was found to be 2.434×10-3 cm-1 s -1.

AB - Pt-Ti and Pb-Pt-Ti thin films were deposited on alumina substrates by sputtering in Ar gas. In this study, an electrodeposited Pb-modified Pt-Ti thin film working electrode was prepared. Optimal sensing conditions were found to be -2.10 V (versus Ag/Ag+ with 0.1 M tetrabutylammonium perchlorate (TBAP) in acetonitrile (AN) solution) sensing potential, 250 rpm agitation rate. At room temperature, the response time was 15 s (90% response time). The correlation of sensing response current, id, and trichloroethylene (TCE) concentration, CL, is id=2.86CL in the range from 100 to 700 ppm TCE. Additionally, the rate constant of (TCE) cathodic reduction was found to be 2.434×10-3 cm-1 s -1.

KW - Electrodeposited Pb-modified Pt-Ti thin film

KW - Sensor

KW - Trichloroethylene

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M3 - 期刊論文

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AN - SCOPUS:2342606443

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SP - 25

EP - 32

JO - Biosensors and Bioelectronics

JF - Biosensors and Bioelectronics

SN - 0956-5663

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Thin film trichloroethylene electrochemical sensor

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