The electrochemical fluorination of acetyl fluoride

D. J. Wasser; P. S. Johnson; F. W. Klink; F. Kucera; Chung Chiun Liu

doi:10.1016/S0022-1139(00)82002-3

The electrochemical fluorination of acetyl fluoride

D. J. Wasser, P. S. Johnson, F. W. Klink, F. Kucera, Chung Chiun Liu

材料科學與工程研究所

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

3 引文斯高帕斯（Scopus）

摘要

The electrochemical fluorination of acetyl fluoride in anhydrous hydrogen fluoride to produce trifluoroacetyl fluoride was investigated in a microprocessor-aided modified Simons' reactor. The product was recovered in acetic acid as trifluoroacetic acid. The experiments were carried out at a controlled anodic potential using a Cu/CuF₂ reference electrode. Product yields of 36 - 45%, current efficiencies of 30 to 50% and energy efficiencies of 11 - 23% were obtained. Experimental results of this investigation are presented and discussed.

原文	???core.languages.en_GB???
頁（從 - 到）	557-569
頁數	13
期刊	Journal of Fluorine Chemistry
卷	35
發行號	3
DOIs	https://doi.org/10.1016/S0022-1139(00)82002-3
出版狀態	已出版 - 4月 1987

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10.1016/S0022-1139(00)82002-3

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abstract = "The electrochemical fluorination of acetyl fluoride in anhydrous hydrogen fluoride to produce trifluoroacetyl fluoride was investigated in a microprocessor-aided modified Simons' reactor. The product was recovered in acetic acid as trifluoroacetic acid. The experiments were carried out at a controlled anodic potential using a Cu/CuF2 reference electrode. Product yields of 36 - 45%, current efficiencies of 30 to 50% and energy efficiencies of 11 - 23% were obtained. Experimental results of this investigation are presented and discussed.",

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AU - Wasser, D. J.

AU - Johnson, P. S.

AU - Klink, F. W.

AU - Kucera, F.

AU - Liu, Chung Chiun

PY - 1987/4

Y1 - 1987/4

N2 - The electrochemical fluorination of acetyl fluoride in anhydrous hydrogen fluoride to produce trifluoroacetyl fluoride was investigated in a microprocessor-aided modified Simons' reactor. The product was recovered in acetic acid as trifluoroacetic acid. The experiments were carried out at a controlled anodic potential using a Cu/CuF2 reference electrode. Product yields of 36 - 45%, current efficiencies of 30 to 50% and energy efficiencies of 11 - 23% were obtained. Experimental results of this investigation are presented and discussed.

AB - The electrochemical fluorination of acetyl fluoride in anhydrous hydrogen fluoride to produce trifluoroacetyl fluoride was investigated in a microprocessor-aided modified Simons' reactor. The product was recovered in acetic acid as trifluoroacetic acid. The experiments were carried out at a controlled anodic potential using a Cu/CuF2 reference electrode. Product yields of 36 - 45%, current efficiencies of 30 to 50% and energy efficiencies of 11 - 23% were obtained. Experimental results of this investigation are presented and discussed.

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DO - 10.1016/S0022-1139(00)82002-3

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EP - 569

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 3

ER -

The electrochemical fluorination of acetyl fluoride

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