The effect of: Cis - Trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers

Yogesh S. Tingare; Suri Babu Akula; Ming Tai Shen; Chaochin Su; Shih Yu Ho; Sheng Han Tsai; Ya Fen Lin; Wen Ren Li

doi:10.1039/c8dt01131a

The effect of: Cis - Trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers

Yogesh S. Tingare, Suri Babu Akula, Ming Tai Shen, Chaochin Su, Shih Yu Ho, Sheng Han Tsai, Ya Fen Lin, Wen Ren Li

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

1 引文斯高帕斯（Scopus）

摘要

New heteroleptic Ru(ii) complexes consisting of pyridylimine as an ancillary ligand were synthesized and characterized for applications in dye sensitized solar cells. Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. The effect of the difference in the configurations of these complexes on their device performances was studied and the sensitizer with a trans arrangement around the metal showed a higher overall conversion efficiency (η) of 7.27% than that of the cis configured complex (η = 2.04%).

原文	???core.languages.en_GB???
頁（從 - 到）	8356-8363
頁數	8
期刊	Dalton Transactions
卷	47
發行號	25
DOIs	https://doi.org/10.1039/c8dt01131a
出版狀態	已出版 - 2018

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10.1039/c8dt01131a

研發嶄新的太陽能電池材料及其製備與應用(1/2)
Li, W.-R. (PI)
1/08/17 → 31/10/18
研究計畫: Research

CCDC 1821991: Experimental Crystal Structure Determination
Tingare, Y. S. (???dataset.roles.dataset.creator???), Akula, S. B. (???dataset.roles.dataset.creator???), Shen, M.-T. (???dataset.roles.dataset.creator???), Su, C. (???dataset.roles.dataset.creator???), Ho, S.-Y. (???dataset.roles.dataset.creator???), Tsai, S.-H. (???dataset.roles.dataset.creator???), Lin, Y.-F. (???dataset.roles.dataset.creator???) & Li, W.-R. (???dataset.roles.dataset.creator???), The Cambridge Structural Database, 2018
DOI: 10.5517/ccdc.csd.cc1z4xxy, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1z4xxy&sid=DataCite
資料集
CCDC 1821992: Experimental Crystal Structure Determination
Tingare, Y. S. (???dataset.roles.dataset.creator???), Akula, S. B. (???dataset.roles.dataset.creator???), Shen, M.-T. (???dataset.roles.dataset.creator???), Su, C. (???dataset.roles.dataset.creator???), Ho, S.-Y. (???dataset.roles.dataset.creator???), Tsai, S.-H. (???dataset.roles.dataset.creator???), Lin, Y.-F. (???dataset.roles.dataset.creator???) & Li, W.-R. (???dataset.roles.dataset.creator???), The Cambridge Structural Database, 2018
DOI: 10.5517/ccdc.csd.cc1z4xyz, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1z4xyz&sid=DataCite
資料集

引用此

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title = "The effect of: Cis - Trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers",

abstract = "New heteroleptic Ru(ii) complexes consisting of pyridylimine as an ancillary ligand were synthesized and characterized for applications in dye sensitized solar cells. Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. The effect of the difference in the configurations of these complexes on their device performances was studied and the sensitizer with a trans arrangement around the metal showed a higher overall conversion efficiency (η) of 7.27% than that of the cis configured complex (η = 2.04%).",

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T2 - Cis - Trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers

AU - Tingare, Yogesh S.

AU - Akula, Suri Babu

AU - Shen, Ming Tai

AU - Su, Chaochin

AU - Ho, Shih Yu

AU - Tsai, Sheng Han

AU - Lin, Ya Fen

AU - Li, Wen Ren

PY - 2018

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N2 - New heteroleptic Ru(ii) complexes consisting of pyridylimine as an ancillary ligand were synthesized and characterized for applications in dye sensitized solar cells. Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. The effect of the difference in the configurations of these complexes on their device performances was studied and the sensitizer with a trans arrangement around the metal showed a higher overall conversion efficiency (η) of 7.27% than that of the cis configured complex (η = 2.04%).

AB - New heteroleptic Ru(ii) complexes consisting of pyridylimine as an ancillary ligand were synthesized and characterized for applications in dye sensitized solar cells. Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. The effect of the difference in the configurations of these complexes on their device performances was studied and the sensitizer with a trans arrangement around the metal showed a higher overall conversion efficiency (η) of 7.27% than that of the cis configured complex (η = 2.04%).

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SN - 1477-9226

VL - 47

SP - 8356

EP - 8363

JO - Dalton Transactions

JF - Dalton Transactions

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ER -

The effect of: Cis - Trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers

摘要

存取文件

指紋

專案

研發嶄新的太陽能電池材料及其製備與應用(1/2)

資料集

CCDC 1821991: Experimental Crystal Structure Determination

CCDC 1821992: Experimental Crystal Structure Determination

引用此