每年專案
摘要
A one-pot, two-staged protocol has been developed for the synthesis of 3-bromoindenes from aryl alkynyl alcohols/sulfonamides and aldehydes. Bromotrimethylsilane (TMSBr) initiated a halo-Prins cyclization reaction to give 3-(bromomethylene)-tetrahydropyrans or -piperidines, which underwent ring-opening and Friedel-Crafts allylation to yield 3-bromoindenes in the presence of Brønsted acids.
原文 | ???core.languages.en_GB??? |
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頁(從 - 到) | 1561-1571 |
頁數 | 11 |
期刊 | Asian Journal of Organic Chemistry |
卷 | 8 |
發行號 | 8 |
DOIs | |
出版狀態 | 已出版 - 8月 2019 |
指紋
深入研究「Synthesis of 3-Bromoindenes from 4-Alkynyl Alcohols/Sulfonamides and Aldehydes via Prins Cyclization, Ring-Opening and Friedel-Crafts Reactions」主題。共同形成了獨特的指紋。專案
- 1 已完成
資料集
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CCDC 1898770: Experimental Crystal Structure Determination
Kotipalli, T. (貢獻者) & Hou, D. (貢獻者), The Cambridge Structural Database, 2019
DOI: 10.5517/ccdc.csd.cc21qtn8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc21qtn8&sid=DataCite
資料集