Synthesis, crystal structure, magnetic susceptibility, and Mössbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound: (H3DETA)[Fe3(C2O4) 2(HPO4)2(PO4)] (DETA = diethylenetriamine)

Yau Chen Jiang; Sue Lein Wang; Kwang Hwa Lii; Ninh Nguyen; Annie Ducouret

doi:10.1021/cm021701t

Synthesis, crystal structure, magnetic susceptibility, and Mössbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound: (H₃DETA)[Fe₃(C₂O₄) ₂(HPO₄)₂(PO₄)] (DETA = diethylenetriamine)

Yau Chen Jiang, Sue Lein Wang, Kwang Hwa Lii, Ninh Nguyen, Annie Ducouret

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

46 引文斯高帕斯（Scopus）

摘要

A mixed-valence organic-inorganic hybrid compound, (H₃DETA) [Fe₃(C₂O₄)₂ (HPO₄)₂(PO₄)] (DETA = diethylenetriamine), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, magnetic susceptibility, ⁵⁷Fe powder absorption Mössbauer spectroscopy, and electric field gradient calculations. It crystallizes in the triclinic space group P1 (No. 2) with a = 9.6367(7) Å, b = 10.1760(7) Å, c = 12.6164(9) Å, α = 86.302(1)°, β = 68.880(1)°, γ = 61.800(1)°, and Z = 2 with R₁ = 0.0397. The structure can be described as layers of trigonal bipyramidal Fe^IIO₅, octahedral Fe^IIIO₆, tetrahedral PO₄ moieties, and monobidentate oxalate ligands, which are pillared through bisbidentate oxalate ligands to form a 3-D framework structure. The title compound is not only the first oxalatophosphate that contains two types of oxalate ligands but also the first example of mixed-valence transition metal oxalatophosphate.

原文	???core.languages.en_GB???
頁（從 - 到）	1633-1638
頁數	6
期刊	Chemistry of Materials
卷	15
發行號	8
DOIs	https://doi.org/10.1021/cm021701t
出版狀態	已出版 - 22 4月 2003

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10.1021/cm021701t

CCDC 214360: Experimental Crystal Structure Determination
Jiang, Y.-C. (???dataset.roles.dataset.creator???), Wang, S.-L. (???dataset.roles.dataset.creator???), Lii, K.-H. (???dataset.roles.dataset.creator???), Nguyen, N. (???dataset.roles.dataset.creator???) & Ducouret, A. (???dataset.roles.dataset.creator???), The Cambridge Structural Database, 2003
DOI: 10.5517/cc761v9, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc761v9&sid=DataCite
資料集

引用此

@article{a042b55544794517afc4587799da082a,

title = "Synthesis, crystal structure, magnetic susceptibility, and M{\"o}ssbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound: (H3DETA)[Fe3(C2O4) 2(HPO4)2(PO4)] (DETA = diethylenetriamine)",

abstract = "A mixed-valence organic-inorganic hybrid compound, (H3DETA) [Fe3(C2O4)2 (HPO4)2(PO4)] (DETA = diethylenetriamine), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, magnetic susceptibility, 57Fe powder absorption M{\"o}ssbauer spectroscopy, and electric field gradient calculations. It crystallizes in the triclinic space group P1 (No. 2) with a = 9.6367(7) {\AA}, b = 10.1760(7) {\AA}, c = 12.6164(9) {\AA}, α = 86.302(1)°, β = 68.880(1)°, γ = 61.800(1)°, and Z = 2 with R1 = 0.0397. The structure can be described as layers of trigonal bipyramidal FeIIO5, octahedral FeIIIO6, tetrahedral PO4 moieties, and monobidentate oxalate ligands, which are pillared through bisbidentate oxalate ligands to form a 3-D framework structure. The title compound is not only the first oxalatophosphate that contains two types of oxalate ligands but also the first example of mixed-valence transition metal oxalatophosphate.",

author = "Jiang, {Yau Chen} and Wang, {Sue Lein} and Lii, {Kwang Hwa} and Ninh Nguyen and Annie Ducouret",

year = "2003",

month = apr,

day = "22",

doi = "10.1021/cm021701t",

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volume = "15",

pages = "1633--1638",

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Synthesis, crystal structure, magnetic susceptibility, and Mössbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound: (H₃DETA)[Fe₃(C₂O₄) ₂(HPO₄)₂(PO₄)] (DETA = diethylenetriamine). / Jiang, Yau Chen; Wang, Sue Lein; Lii, Kwang Hwa 等.
於: Chemistry of Materials, 卷 15, 編號 8, 22.04.2003, p. 1633-1638.

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

TY - JOUR

T1 - Synthesis, crystal structure, magnetic susceptibility, and Mössbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound

T2 - (H3DETA)[Fe3(C2O4) 2(HPO4)2(PO4)] (DETA = diethylenetriamine)

AU - Jiang, Yau Chen

AU - Wang, Sue Lein

AU - Lii, Kwang Hwa

AU - Nguyen, Ninh

AU - Ducouret, Annie

PY - 2003/4/22

Y1 - 2003/4/22

N2 - A mixed-valence organic-inorganic hybrid compound, (H3DETA) [Fe3(C2O4)2 (HPO4)2(PO4)] (DETA = diethylenetriamine), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, magnetic susceptibility, 57Fe powder absorption Mössbauer spectroscopy, and electric field gradient calculations. It crystallizes in the triclinic space group P1 (No. 2) with a = 9.6367(7) Å, b = 10.1760(7) Å, c = 12.6164(9) Å, α = 86.302(1)°, β = 68.880(1)°, γ = 61.800(1)°, and Z = 2 with R1 = 0.0397. The structure can be described as layers of trigonal bipyramidal FeIIO5, octahedral FeIIIO6, tetrahedral PO4 moieties, and monobidentate oxalate ligands, which are pillared through bisbidentate oxalate ligands to form a 3-D framework structure. The title compound is not only the first oxalatophosphate that contains two types of oxalate ligands but also the first example of mixed-valence transition metal oxalatophosphate.

AB - A mixed-valence organic-inorganic hybrid compound, (H3DETA) [Fe3(C2O4)2 (HPO4)2(PO4)] (DETA = diethylenetriamine), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, magnetic susceptibility, 57Fe powder absorption Mössbauer spectroscopy, and electric field gradient calculations. It crystallizes in the triclinic space group P1 (No. 2) with a = 9.6367(7) Å, b = 10.1760(7) Å, c = 12.6164(9) Å, α = 86.302(1)°, β = 68.880(1)°, γ = 61.800(1)°, and Z = 2 with R1 = 0.0397. The structure can be described as layers of trigonal bipyramidal FeIIO5, octahedral FeIIIO6, tetrahedral PO4 moieties, and monobidentate oxalate ligands, which are pillared through bisbidentate oxalate ligands to form a 3-D framework structure. The title compound is not only the first oxalatophosphate that contains two types of oxalate ligands but also the first example of mixed-valence transition metal oxalatophosphate.

UR - http://www.scopus.com/inward/record.url?scp=0037461243&partnerID=8YFLogxK

U2 - 10.1021/cm021701t

DO - 10.1021/cm021701t

M3 - 期刊論文

AN - SCOPUS:0037461243

SN - 0897-4756

VL - 15

SP - 1633

EP - 1638

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 8

ER -

Synthesis, crystal structure, magnetic susceptibility, and Mössbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound: (H3DETA)[Fe3(C2O4) 2(HPO4)2(PO4)] (DETA = diethylenetriamine)

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指紋

資料集

CCDC 214360: Experimental Crystal Structure Determination

引用此

Synthesis, crystal structure, magnetic susceptibility, and Mössbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound: (H₃DETA)[Fe₃(C₂O₄) ₂(HPO₄)₂(PO₄)] (DETA = diethylenetriamine)