每年專案
摘要
A new cyclic stilbene derivative, 6-(4-(diphenylamino)-phenyl)-N,N-diphenyl-7,8-dihydronaphthalen-2-amine (D2PDN), featuring a quadrupolar system having electron-donating substituents (NPh2), was synthesized and characterized in this study. The fluorescence quantum yield was 89% (under air) and 99% (under argon) in toluene. The two-photon (2P) cross-section was determined to be 166 GM at 700 nm using 2P-excitation fluorescence method. The 2P-responsive chromophore in near-infrared region has reversible oxidation signals at 0.17, 0.28, and 0.53 V vs Fc0/Fc+. Compound D2PDN, E*ox = 12.83 V, was found to be a simultaneous 2P-responsive photoredox catalyst.
原文 | ???core.languages.en_GB??? |
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頁(從 - 到) | 846-849 |
頁數 | 4 |
期刊 | Chemistry Letters |
卷 | 52 |
發行號 | 11 |
DOIs | |
出版狀態 | 已出版 - 2023 |
指紋
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