Synthesis and structural characterization of a series of Co(II) NNN pincer complexes

Theodore Gerard, Graden Snyder, Matthias Zeller, Diane A. Dickie, Wei Tsung Lee

研究成果: 雜誌貢獻期刊論文同行評審

摘要

Several new Co(II) complexes supported by CztBu(PyriPr)2 ligand(s) in various ligand-to-metal ratios are reported. The synthesis and characterization of CztBu(PyriPr)2Co (1) completes a series of analogous compounds (CztBu(PyriPr)2M, M = Fe(II), Co(II), Ni(II)), offering insights into chemical trends across late first-row transition metal complexes. Additionally, chemical oxidation of (CztBu(PyriPr)2)2Co (2) gave complex 5, in which unprecedented, cobalt-facilitated C[sbnd]C coupling of pyrazole moieties has occurred.

原文???core.languages.en_GB???
文章編號116155
期刊Polyhedron
228
DOIs
出版狀態已出版 - 1 12月 2022

指紋

深入研究「Synthesis and structural characterization of a series of Co(II) NNN pincer complexes」主題。共同形成了獨特的指紋。

引用此