Synthesis and crystal structure of Ca(VO)2(PO4)2

K. H. Lii, B. R. Chueh, H. Y. Kang, S. L. Wang

研究成果: 雜誌貢獻期刊論文同行評審

44 引文 斯高帕斯(Scopus)

摘要

A new phosphate, Ca(VO)2(PO4)2, was synthesized hydrothermally and its structure was determined from single-crystal X-ray diffraction data. It crystallizes in the noncentrosymmetric orthorhombic space group Fdd2 with a = 11.795(4), b = 15.784(6), c = 7.190(4)Å, Z = 8, and R = 0.0346. The structure consists of infinite chains of trans-corner-sharing VO6 octahedra cross-linked by phosphate groups to form a 3-dimensional network. These chains have alternating short and long V{single bond}O bonds. The network contains intersecting channels where the Ca2+ cations are located. The structure is compared with those of the AVOPO4 (A =alkali metal) family.

原文???core.languages.en_GB???
頁(從 - 到)72-77
頁數6
期刊Journal of Solid State Chemistry
99
發行號1
DOIs
出版狀態已出版 - 7月 1992

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