Synthesis and characterization of new ferrocenylamine sulfide and selenide complexes

Ahmad A. Naiini, Lai Chung-Kung, Carl H. Brubaker

研究成果: 雜誌貢獻期刊論文同行評審

2 引文 斯高帕斯(Scopus)

摘要

Some hitherto unknown ferrocenylamine sulfides and selenides, (η5-C5H4-SR)Fe(η5-C5H3-1-CH2NMe2- 2-SR) (R = Et, n-Pr, i-Pr, n-Bu, t-Bu, i-Pent),(R,S)(η5- C5H5)Fe(η5-C5H3-1-CH(Me)NMe2-2-SeR) (R = Ph, 4-Cl-Ph), (R,S)(η5-C5H4-SR)Fe(η5-C5H3-1-CH(Me)- NMe2-2-SR) (R = Et, n-Pr, i-Pr, n-Bu, s-Bu, t-Bu, i-Pent), (R,S)(η5-C5H4-SeMe)Fe(η5-C5H3-1-CH(Me)- NMe2-2-SeMe), (S,R)(η5-C5H4-SR)Fe(η5-C5H3-1- CH(Me)NMe2-2-SR) (R = Et, n-Pr, i-Pr, n-Bu, s-Bu, t-Bu, i-Pent) and (S,R)(η5-C5H4-SeMe)Fe(η5-C5H3-1- CH(Me)NMe2-2-SeMe) have been synthesized via the lithiation of proper ferrocene precursors, followed by treatment with appropriate disulfides and diselenides. These compounds, which are air stable, have been characterized by 1H NMR, 13C NMR, IR, MS and elemental analysis.

原文???core.languages.en_GB???
頁(從 - 到)241-244
頁數4
期刊Inorganica Chimica Acta
160
發行號2
DOIs
出版狀態已出版 - 15 6月 1989

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