Study of multiple interactions in mesoporous composite PEO electrolytes

M. Jaipal Reddy, Peter P. Chu, U. V.Subba Rao

研究成果: 雜誌貢獻期刊論文同行評審

33 引文 斯高帕斯(Scopus)

摘要

This paper discusses the FT-infrared (IR) and NMR spectroscopy results of a mesoporous silica (SBA-15) composite poly(ethylene oxide) (PEO) solid lithium polymer electrolyte. The changes in COC, CH, and ClO4 stretching IR vibrational modes indicated a combination of multiple interactions through Lewis acid-base reactions which interrupt the PEO crystalline structure. Higher salt disassociation by SBA-15 is also apparent from ClO4 vibrational band mode. NMR studies indicated three types of Li ion environments; the first one is Li ions within the conventional amorphous PEO, the second is Li ions on the surface of mesoporous SBA-15 and the third is Li ions trapped along with PEO in the nano-tubular channels of SBA-15. Annealing leads to interaction of more PEO and lithium ions with the SBA-15 and free ions for conduction, as reflected in the 7Li variable temperature (VT)-NMR measurements and variable temperature ion conductivity.

原文???core.languages.en_GB???
頁(從 - 到)614-619
頁數6
期刊Journal of Power Sources
158
發行號1
DOIs
出版狀態已出版 - 14 7月 2006

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