Structural, optical and excitonic properties of MAxCs1-xPb(IxBr1-x)3 alloy thin films and their application in solar cells

Sheng Hsiung Chang; Pin Chia Tseng; Shou En Chiang; Jia Ren Wu; Yan Ta Chen; Ching Ju Chen; Chi Tsu Yuan; Sheng Hui Chen

doi:10.1016/j.solmat.2020.110478

Structural, optical and excitonic properties of MA_xCs_1-xPb(I_xBr_1-x)₃ alloy thin films and their application in solar cells

Sheng Hsiung Chang, Pin Chia Tseng, Shou En Chiang, Jia Ren Wu, Yan Ta Chen, Ching Ju Chen, Chi Tsu Yuan, Sheng Hui Chen

光電科學與工程學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

24 引文斯高帕斯（Scopus）

摘要

The structural, optical and excitonic characteristics of MA_xCs_1-xPb(I_xBr_1-x)₃ crystal thin films were investigated by using the X-ray diffraction patterns, scanning electron microscopic images, absorbance spectra and photoluminescence (PL) spectra. The time-dependent PL spectra shows that the MA_0.8Cs_0.2Pb(I_0.8Br_0.2)₃ crystal thin film is a photo-stable light absorbing material, which results in an efficient and stable perovskite solar cell without the additional encapsulation. The highest power conversion efficiency (PCE) of MA_0.8Cs_0.2Pb(I_0.8Br_0.2)₃ solar cells is 10.02%. In addition, the PCE decreases slowly toward a stable value (5.71%) for more than 120 days under moderate environment conditions (55–60 RH%).

原文	???core.languages.en_GB???
文章編號	110478
期刊	Solar Energy Materials and Solar Cells
卷	210
DOIs	https://doi.org/10.1016/j.solmat.2020.110478
出版狀態	已出版 - 15 6月 2020

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10.1016/j.solmat.2020.110478

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title = "Structural, optical and excitonic properties of MAxCs1-xPb(IxBr1-x)3 alloy thin films and their application in solar cells",

abstract = "The structural, optical and excitonic characteristics of MAxCs1-xPb(IxBr1-x)3 crystal thin films were investigated by using the X-ray diffraction patterns, scanning electron microscopic images, absorbance spectra and photoluminescence (PL) spectra. The time-dependent PL spectra shows that the MA0.8Cs0.2Pb(I0.8Br0.2)3 crystal thin film is a photo-stable light absorbing material, which results in an efficient and stable perovskite solar cell without the additional encapsulation. The highest power conversion efficiency (PCE) of MA0.8Cs0.2Pb(I0.8Br0.2)3 solar cells is 10.02%. In addition, the PCE decreases slowly toward a stable value (5.71%) for more than 120 days under moderate environment conditions (55–60 RH%).",

keywords = "MACsPb(IBr), Stable perovskite solar cells, Time-dependent photoluminescence",

author = "Chang, {Sheng Hsiung} and Tseng, {Pin Chia} and Chiang, {Shou En} and Wu, {Jia Ren} and Chen, {Yan Ta} and Chen, {Ching Ju} and Yuan, {Chi Tsu} and Chen, {Sheng Hui}",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

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doi = "10.1016/j.solmat.2020.110478",

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T1 - Structural, optical and excitonic properties of MAxCs1-xPb(IxBr1-x)3 alloy thin films and their application in solar cells

AU - Chang, Sheng Hsiung

AU - Tseng, Pin Chia

AU - Chiang, Shou En

AU - Wu, Jia Ren

AU - Chen, Yan Ta

AU - Chen, Ching Ju

AU - Yuan, Chi Tsu

AU - Chen, Sheng Hui

PY - 2020/6/15

Y1 - 2020/6/15

N2 - The structural, optical and excitonic characteristics of MAxCs1-xPb(IxBr1-x)3 crystal thin films were investigated by using the X-ray diffraction patterns, scanning electron microscopic images, absorbance spectra and photoluminescence (PL) spectra. The time-dependent PL spectra shows that the MA0.8Cs0.2Pb(I0.8Br0.2)3 crystal thin film is a photo-stable light absorbing material, which results in an efficient and stable perovskite solar cell without the additional encapsulation. The highest power conversion efficiency (PCE) of MA0.8Cs0.2Pb(I0.8Br0.2)3 solar cells is 10.02%. In addition, the PCE decreases slowly toward a stable value (5.71%) for more than 120 days under moderate environment conditions (55–60 RH%).

AB - The structural, optical and excitonic characteristics of MAxCs1-xPb(IxBr1-x)3 crystal thin films were investigated by using the X-ray diffraction patterns, scanning electron microscopic images, absorbance spectra and photoluminescence (PL) spectra. The time-dependent PL spectra shows that the MA0.8Cs0.2Pb(I0.8Br0.2)3 crystal thin film is a photo-stable light absorbing material, which results in an efficient and stable perovskite solar cell without the additional encapsulation. The highest power conversion efficiency (PCE) of MA0.8Cs0.2Pb(I0.8Br0.2)3 solar cells is 10.02%. In addition, the PCE decreases slowly toward a stable value (5.71%) for more than 120 days under moderate environment conditions (55–60 RH%).

KW - MACsPb(IBr)

KW - Stable perovskite solar cells

KW - Time-dependent photoluminescence

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U2 - 10.1016/j.solmat.2020.110478

DO - 10.1016/j.solmat.2020.110478

M3 - 期刊論文

AN - SCOPUS:85079880686

SN - 0927-0248

VL - 210

JO - Solar Energy Materials and Solar Cells

JF - Solar Energy Materials and Solar Cells

M1 - 110478

ER -

Structural, optical and excitonic properties of MAxCs1-xPb(IxBr1-x)3 alloy thin films and their application in solar cells

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Structural, optical and excitonic properties of MA_xCs_1-xPb(I_xBr_1-x)₃ alloy thin films and their application in solar cells