摘要
Materials with non-linear optical (NLO) properties play an important role in the construction of electronic devices for optical communications, optical data processing and data storage. With this aim in mind, a Zn(II)-based metal-organic framework {[Zn2 (nica)2 (bpy)1.5(H2O)]?0.5(bpy)?3H2O}n (1), was synthesized using 4,4-bipyridine (bpy) and a potentially bidentate ligand, 2-hydroxynicotinic acid (H2nica) with a salicylate binding moiety. A single-crystal X-ray diffraction analysis revealed that compound 1 crystallized in the orthorhombic space group Fdd2 and was composed of a three dimensional porous framework. Since Fdd2 belonged to a class of non-centrosymmetric space groups, we therefore investigated the non-linear optical behaviour of compound 1. Photoluminescence studies revealed that compound 1 exhibited a blue light emission with a maxima at 457 nm.
原文 | ???core.languages.en_GB??? |
---|---|
頁(從 - 到) | 8941-8951 |
頁數 | 11 |
期刊 | Molecules |
卷 | 20 |
發行號 | 5 |
DOIs | |
出版狀態 | 已出版 - 2015 |
指紋
深入研究「Structural characteristics and non-linear optical behaviour of a 2-Hydroxynicotinate-containing zinc-based metal-organic framework」主題。共同形成了獨特的指紋。資料集
-
CCDC 1056788: Experimental Crystal Structure Determination
Mendiratta, S. (???dataset.roles.dataset.creator???), Lee, C. (???dataset.roles.dataset.creator???), Lee, S. (???dataset.roles.dataset.creator???), Kao, Y. (???dataset.roles.dataset.creator???), Chang, B. (???dataset.roles.dataset.creator???), Lo, Y. (???dataset.roles.dataset.creator???) & Lu, K. (???dataset.roles.dataset.creator???), The Cambridge Structural Database, 2015
DOI: 10.5517/cc14gny6, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc14gny6&sid=DataCite
資料集