Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF

Li Wei Lee, Ya Chuan Kao, Mei Ying Chung, Bor Chen Chang, Gene Hsiang Lee, Shie Ming Peng, Chih Min Wang, Yen Hsiang Liu, Sheng Long Lee, Kuang Lieh Lu

研究成果: 雜誌貢獻期刊論文同行評審

5 引文 斯高帕斯(Scopus)

摘要

An SHG-active noncentrosymmetric (3,4)-connected Zn(ii)-organic framework, {[Zn 2 (4-abpt)(3,4-pydc) 2 ]·2DMAc·3MeOH·H 2 O} n (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn II ions with Cu II ions while retaining the integrity of the network.

原文???core.languages.en_GB???
頁(從 - 到)1950-1954
頁數5
期刊Dalton Transactions
48
發行號6
DOIs
出版狀態已出版 - 2019

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