Rare earth metal squarates incorporating ethylene glycol ligand with a three-dimensional framework structure: RE(C4O4) 1.5(C2H6O2) (RE = Y, La-Nd, Sm-Lu)

Yen Shen Liu; Ming Feng Tang; Kwang Hwa Lii

doi:10.1039/b911962k

Rare earth metal squarates incorporating ethylene glycol ligand with a three-dimensional framework structure: RE(C₄O₄) _1.5(C₂H₆O₂) (RE = Y, La-Nd, Sm-Lu)

Yen Shen Liu, Ming Feng Tang, Kwang Hwa Lii

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

18 引文斯高帕斯（Scopus）

摘要

Fifteen isostructural rare earth metal squarates incorporating ethylene glycol ligand with the formula RE(C₄O₄) _1.5(C₂H₆O₂) (RE = Y, La-Nd, Sm-Lu) have been synthesized under hydrothermal conditions and structurally characterized by single-crystal and powder X-ray diffraction, ¹³C CPMAS NMR, absorption spectroscopy, and magnetic susceptibility. A variable-temperature in situ powder X-ray diffraction study on the Ce compound was also performed to determine its thermal stability. Each RE³⁺ cation in the structure is bonded to six squarate anions and one neutral ethylene glycol chelate, and each C₄O₄^2- anion coordinates to four RE³⁺ cations such that a new 3-D framework is formed. They are the first examples of organic-inorganic hybrids which contain both squarate and ethylene glycol ligands.

原文	???core.languages.en_GB???
頁（從 - 到）	9781-9786
頁數	6
期刊	Dalton Transactions
發行號	44
DOIs	https://doi.org/10.1039/b911962k
出版狀態	已出版 - 2009

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10.1039/b911962k

CCDC 737279: Experimental Crystal Structure Determination
Liu, Y.-S. (???dataset.roles.dataset.creator???), Tang, M.-F. (???dataset.roles.dataset.creator???) & Lii, K.-H. (???dataset.roles.dataset.creator???), The Cambridge Structural Database, 2010
DOI: 10.5517/ccsr66x, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsr66x&sid=DataCite
資料集
CCDC 737271: Experimental Crystal Structure Determination
Liu, Y.-S. (???dataset.roles.dataset.creator???), Tang, M.-F. (???dataset.roles.dataset.creator???) & Lii, K.-H. (???dataset.roles.dataset.creator???), The Cambridge Structural Database, 2010
DOI: 10.5517/ccsr5ym, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsr5ym&sid=DataCite
資料集
CCDC 737272: Experimental Crystal Structure Determination
Liu, Y.-S. (???dataset.roles.dataset.creator???), Tang, M.-F. (???dataset.roles.dataset.creator???) & Lii, K.-H. (???dataset.roles.dataset.creator???), The Cambridge Structural Database, 2010
DOI: 10.5517/ccsr5zn, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsr5zn&sid=DataCite
資料集

引用此

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abstract = "Fifteen isostructural rare earth metal squarates incorporating ethylene glycol ligand with the formula RE(C4O4) 1.5(C2H6O2) (RE = Y, La-Nd, Sm-Lu) have been synthesized under hydrothermal conditions and structurally characterized by single-crystal and powder X-ray diffraction, 13C CPMAS NMR, absorption spectroscopy, and magnetic susceptibility. A variable-temperature in situ powder X-ray diffraction study on the Ce compound was also performed to determine its thermal stability. Each RE3+ cation in the structure is bonded to six squarate anions and one neutral ethylene glycol chelate, and each C4O42- anion coordinates to four RE3+ cations such that a new 3-D framework is formed. They are the first examples of organic-inorganic hybrids which contain both squarate and ethylene glycol ligands.",

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AB - Fifteen isostructural rare earth metal squarates incorporating ethylene glycol ligand with the formula RE(C4O4) 1.5(C2H6O2) (RE = Y, La-Nd, Sm-Lu) have been synthesized under hydrothermal conditions and structurally characterized by single-crystal and powder X-ray diffraction, 13C CPMAS NMR, absorption spectroscopy, and magnetic susceptibility. A variable-temperature in situ powder X-ray diffraction study on the Ce compound was also performed to determine its thermal stability. Each RE3+ cation in the structure is bonded to six squarate anions and one neutral ethylene glycol chelate, and each C4O42- anion coordinates to four RE3+ cations such that a new 3-D framework is formed. They are the first examples of organic-inorganic hybrids which contain both squarate and ethylene glycol ligands.

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Rare earth metal squarates incorporating ethylene glycol ligand with a three-dimensional framework structure: RE(C4O4) 1.5(C2H6O2) (RE = Y, La-Nd, Sm-Lu)

摘要

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指紋

資料集

CCDC 737279: Experimental Crystal Structure Determination

CCDC 737271: Experimental Crystal Structure Determination

CCDC 737272: Experimental Crystal Structure Determination

引用此

Rare earth metal squarates incorporating ethylene glycol ligand with a three-dimensional framework structure: RE(C₄O₄) _1.5(C₂H₆O₂) (RE = Y, La-Nd, Sm-Lu)