Preparation of polyfunctional arylmagnesium reagents bearing a triazene moiety. A new carbazole synthesis

Ching Yuan Liu; Paul Knochel

doi:10.1021/ol0505454

Preparation of polyfunctional arylmagnesium reagents bearing a triazene moiety. A new carbazole synthesis

Ching Yuan Liu, Paul Knochel

化學工程與材料工程學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

105 引文斯高帕斯（Scopus）

摘要

(Chemical Equation Presented) The reaction of iodo- or bromo-substituted aryltriazenes with i-PrMgCl·LiCl generates the corresponding magnesiated derivatives which react with various electrophiles (acid chlorides, 3-iodoenones, allylic halides, aldehydes) affording polyfunctional triazenes. They can be readily converted to the corresponding polyfunctional aryl iodides. This new synthetic strategy was applied to prepare functionalized carbazoles.

原文	???core.languages.en_GB???
頁（從 - 到）	2543-2546
頁數	4
期刊	Organic Letters
卷	7
發行號	13
DOIs	https://doi.org/10.1021/ol0505454
出版狀態	已出版 - 2005

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10.1021/ol0505454

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AB - (Chemical Equation Presented) The reaction of iodo- or bromo-substituted aryltriazenes with i-PrMgCl·LiCl generates the corresponding magnesiated derivatives which react with various electrophiles (acid chlorides, 3-iodoenones, allylic halides, aldehydes) affording polyfunctional triazenes. They can be readily converted to the corresponding polyfunctional aryl iodides. This new synthetic strategy was applied to prepare functionalized carbazoles.

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M3 - 期刊論文

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Preparation of polyfunctional arylmagnesium reagents bearing a triazene moiety. A new carbazole synthesis

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