Preparation of polyfunctional aryl triazenes via a direct insertion reaction of Zn in the presence of LiCl

Ching Yuan Liu, Paul Knochel

研究成果: 雜誌貢獻期刊論文同行評審

11 引文 斯高帕斯(Scopus)

摘要

A direct zinc insertion of functionalized iodo- or bromophenyl triazenes with zinc dust in the presence of LiCl generates the corresponding arylzinc derivatives which react with a variety of electrophiles such as allylic bromides, acid chlorides, TsCN, and aryl halides providing polyfunctional aryl triazenes in good yields. Two successive zinc insertion reactions into diiodophenyl triazenes have also been achieved.

原文???core.languages.en_GB???
頁(從 - 到)2081-2085
頁數5
期刊Synlett
發行號13
DOIs
出版狀態已出版 - 13 8月 2007

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