TY - JOUR

T1 - Phase diagram for an attractive square-well plus a linear tail potential within the van der Waals-like theory

AU - Wu, K. L.

AU - Chang, C. C.

AU - Lai, S. K.

PY - 2004/4/7

Y1 - 2004/4/7

N2 - The phase equilibrium behavior of a typical colloidal dispersion by the van der Waals-like theory was studied. In this theory, the colloid-colloid potential is split into two parts: a repulsive part modeled by the hard-core potential and an attractive part modeled by the square-well potential corrected by a linear tail. The theory is numerically elegant since the colloidal free energy is analytic and, physically, the model can be used to study the role played by the strength and range of interactions on the formation of coexisting phases. The effect of the strength of the interaction can be accounted for by varying the width of the square-well potential (simulated by γ parameter) while the range of the interaction - by changing the "slope" of the linear potential (simulated by λ parameter). In this work, we consider three separate cases. First, we fixed the threshold values γth, being γthLL = 0.221 for liquid-liquid and γthSS = 0.0329 for solid-solid, and increased λ to examine the appearance of the liquid-liquid and solid-solid coexistence curves which were both calculated with respect to their liquid-solid counterparts. Second, we fixed the threshold values λth, being λthLL = 0.325 for liquid-liquid and λthSS = 0.0456 for solid-solid, and increased γ (keeping the λ-slope unchanged) to bring in the strength of the interaction. In these two cases, the calculations showed that a switching on of λ or γ has the consequence of inducing stable liquid-liquid or metastable solid-solid coexisting phases. Finally, we maintained a given γ plus λ. Here the calculated liquid-liquid and solid-solid phase diagrams can be analyzed in finer details to exhibit the combined influences of the strength and range of interactions.

AB - The phase equilibrium behavior of a typical colloidal dispersion by the van der Waals-like theory was studied. In this theory, the colloid-colloid potential is split into two parts: a repulsive part modeled by the hard-core potential and an attractive part modeled by the square-well potential corrected by a linear tail. The theory is numerically elegant since the colloidal free energy is analytic and, physically, the model can be used to study the role played by the strength and range of interactions on the formation of coexisting phases. The effect of the strength of the interaction can be accounted for by varying the width of the square-well potential (simulated by γ parameter) while the range of the interaction - by changing the "slope" of the linear potential (simulated by λ parameter). In this work, we consider three separate cases. First, we fixed the threshold values γth, being γthLL = 0.221 for liquid-liquid and γthSS = 0.0329 for solid-solid, and increased λ to examine the appearance of the liquid-liquid and solid-solid coexistence curves which were both calculated with respect to their liquid-solid counterparts. Second, we fixed the threshold values λth, being λthLL = 0.325 for liquid-liquid and λthSS = 0.0456 for solid-solid, and increased γ (keeping the λ-slope unchanged) to bring in the strength of the interaction. In these two cases, the calculations showed that a switching on of λ or γ has the consequence of inducing stable liquid-liquid or metastable solid-solid coexisting phases. Finally, we maintained a given γ plus λ. Here the calculated liquid-liquid and solid-solid phase diagrams can be analyzed in finer details to exhibit the combined influences of the strength and range of interactions.

UR - http://www.scopus.com/inward/record.url?scp=2142816694&partnerID=8YFLogxK

U2 - 10.1039/b314333n

DO - 10.1039/b314333n

M3 - 期刊論文

AN - SCOPUS:2142816694

VL - 6

SP - 1369

EP - 1374

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 7

ER -