Organic-inorganic hybrid zinc phosphate with 28-ring channels

Chih Min Wang, Li Wei Lee, Tsung Yuan Chang, Yen Chieh Chen, Hsiu Mei Lin, Kuang Lieh Lu, Kwang Hwa Lii

研究成果: 雜誌貢獻期刊論文同行評審

34 引文 斯高帕斯(Scopus)


An organic-inorganic hybrid zinc phosphate with 28-ring channels was synthesized by use of an organic ligand instead of organic amine template under a hydro( solvo)thermal condition. This crystalline zinc phosphate contains large channels constructed from 28 zinc and phosphate tetrahedral units. The walls of the channels consist of two types of zincophosphate chains, in which the Zn atoms are coordinated by 2,4,5-tri(4-pyridyl)-imidazole ligands as pendent groups. This compound exhibits yellow emission and interesting properties of removing cobalt, cadmium, and mercury cations from aqueous solution. A new two-dimensional organic-inorganic hybrid zincophosphate was also obtained by changing the solvent mixture ratios in the synthesis.

頁(從 - 到)1878-1881
期刊Chemistry - A European Journal
出版狀態已出版 - 26 1月 2015


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