New highly conductive organic-inorganic hybrid electrolytes based on star-branched silica based architectures

Diganta Saikia, Hao Yiang Wu, Chi Pin Lin, Yu Chi Pan, Jason Fang, Li Duan Tsai, George T.K. Fey, Hsien Ming Kao

研究成果: 雜誌貢獻期刊論文同行評審

27 引文 斯高帕斯(Scopus)

摘要

A new type of organic-inorganic hybrid electrolyte has been developed by a sol-gel process through the reaction of cyanuric chloride with poly(oxyalkylene) diamine and 3-isocyanatepropyltriethoxysilane, followed by co-condensation of 2-[methoxy(polyethyleneoxy)propyl]trimethoxysilane. A maximum ionic conductivity of 1.0 × 10-4 Scm-1 at 30°C has been achieved with the solid hybrid electrolyte. The results of solid-state NMR not only confirm the structural framework of the hybrids, but also provide a microscopic view of the effects of salt concentrations on the dynamic behavior of the polymer chains. The hybrid materials are blended with PVdF-HFP to form the blend hybrid membrane, followed by plasticization with various electrolyte solvents, with the purpose of increasing ionic conductivity. The plasticized blend hybrid electrolyte exhibits a maximum room temperature ionic conductivity of 8.8 × 10-3 Scm-1. Such a high ionic conductivity allows it as a potential candidate for applications in lithium ion batteries.

原文???core.languages.en_GB???
頁(從 - 到)6008-6020
頁數13
期刊Polymer
53
發行號26
DOIs
出版狀態已出版 - 7 12月 2012

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