New electronic spectra of the HCCI and DCCI Ã-X̃ vibronic bands

Chia Shih Lin; Ying En Chen; Bor Chen Chang

doi:10.1063/1.1779572

New electronic spectra of the HCCI and DCCI Ã-X̃ vibronic bands

Chia Shih Lin, Ying En Chen, Bor Chen Chang

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

41 引文斯高帕斯（Scopus）

摘要

The electron spectra of the HCCl and DCCl Ã-X̃ vibronic bands were acquired using an intensified charge-coupled device detector. It was observed that dispersed fluorescence spectra exhibited the vibrational structure up to ≈6000 cm^-1 above the zero-point level. Detailed vibrational parameters including anharmonicities and bend-stretch vibrational coupling constants were obtained. The triplet singlet gap was determined to be at ≈2167 cm^-1 in HCCl and 2187 cm^-1 in DCCl.

原文	???core.languages.en_GB???
頁（從 - 到）	4164-4170
頁數	7
期刊	Journal of Chemical Physics
卷	121
發行號	9
DOIs	https://doi.org/10.1063/1.1779572
出版狀態	已出版 - 1 9月 2004

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10.1063/1.1779572

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abstract = "The electron spectra of the HCCl and DCCl {\~A}-{\~X} vibronic bands were acquired using an intensified charge-coupled device detector. It was observed that dispersed fluorescence spectra exhibited the vibrational structure up to ≈6000 cm-1 above the zero-point level. Detailed vibrational parameters including anharmonicities and bend-stretch vibrational coupling constants were obtained. The triplet singlet gap was determined to be at ≈2167 cm-1 in HCCl and 2187 cm-1 in DCCl.",

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N2 - The electron spectra of the HCCl and DCCl Ã-X̃ vibronic bands were acquired using an intensified charge-coupled device detector. It was observed that dispersed fluorescence spectra exhibited the vibrational structure up to ≈6000 cm-1 above the zero-point level. Detailed vibrational parameters including anharmonicities and bend-stretch vibrational coupling constants were obtained. The triplet singlet gap was determined to be at ≈2167 cm-1 in HCCl and 2187 cm-1 in DCCl.

AB - The electron spectra of the HCCl and DCCl Ã-X̃ vibronic bands were acquired using an intensified charge-coupled device detector. It was observed that dispersed fluorescence spectra exhibited the vibrational structure up to ≈6000 cm-1 above the zero-point level. Detailed vibrational parameters including anharmonicities and bend-stretch vibrational coupling constants were obtained. The triplet singlet gap was determined to be at ≈2167 cm-1 in HCCl and 2187 cm-1 in DCCl.

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New electronic spectra of the HCCI and DCCI Ã-X̃ vibronic bands

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