Monte Carlo simulations of chain dynamics in polymer brushes

Kurt Binder, Pik Yin Lai, Joachim Wittmer

研究成果: 雜誌貢獻期刊論文同行評審

43 引文 斯高帕斯(Scopus)


The bond-fluctuation model of polymer chains has been used to study layers of end-grafted polymers anchoring at repulsive walls for a broad range of chain length, grafting densities and solvent quality. The dynamics of monomers and associated relaxation times are investigated and interpreted by phenomenological theories and scaling arguments. The case is also considered where a chain is cut off from its anchor point and the chain is subsequently expelled from the brush. Both the velocity with which the chain leaves the brush and the associated conformational changes (chain contraction etc.) are analysed and interpreted in terms of recent theoretical concepts.

頁(從 - 到)97-109
期刊Faraday Discussions
出版狀態已出版 - 1994


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