Mo3P5SiO19: A molybdenum phosphate containing a confacial bioctahedral molybdenum(III) dimer with a Mo‒Mo bond

S. L. Wang, C. C. Wang, K. H. Lii

研究成果: 雜誌貢獻期刊論文同行評審

23 引文 斯高帕斯(Scopus)

摘要

The crystal structure of Mo3P5SiO19 has been determined from single-crystal X-ray diffraction data. Mo3P5SiO19 crystallizes in the hexagonal space groupP63 (No. 173) witha = b = 14.692(4)A °,c = 7.394(4)A °,Z = 4, R = 0.043 (Rw = 0.034) for 1477 reflections withI > 3 σ (I). The structure contains an unusual confacial bioctahedral Mo2O9 cluster with a Mo{single bond}Mo bond.

原文???core.languages.en_GB???
頁(從 - 到)409-413
頁數5
期刊Journal of Solid State Chemistry
74
發行號2
DOIs
出版狀態已出版 - 6月 1988

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