Ambient noise is typically used to estimate seismic site effects and velocity profiles instead of earthquake recordings, especially in areas with limited seismic data. The dominant Horizontal to Vertical Spectral Ratio (HVSR) frequency of ambient noise is correlated to Vs30, which is the average S-wave velocity in the top 30 m. Vs30 is a widely used parameter for defining seismic amplification in earthquake engineering. HVSR can detect the vertical discontinuity of velocities, that is, the interfaces between hard bedrock and soft sediments. In southwestern Taiwan most strong motion stations are located in the plains and show a dominant frequency lower than 3 Hz. Several stations near the coast have low dominant frequencies of less than 1 Hz. The dominant frequencies are higher than 4 Hz at piedmont stations. The stations in the mountains with dominant frequencies over 8 Hz are typically located on very hard sites. This study analyzed the HVSR characteristics under different seismic site conditions considering the Vs30 from previous study (Kuo et al. 2012). The result implies that HVSRs are a better tool than Vs30 to classify the sites where bedrock is deeper than 30 m. Furthermore, we found a linear correlation between Vs30 and dominant HVSR frequency which could be used as a proxy of Vs30. The Vs30 map in this area was derived using the Engineering Geological Database for Taiwan Strong Motion Instrumentation Program (EGDT). The comparable distribution pattern between the dominant frequency and Vs30 demonstrate that HVSR can recognize S-wave velocity properties at the shallow subsurface.