Intercalation of polyfuran in FeOCl.

C. G. Wu; H. O. Marcy; D. C. DeGroot; J. L. Schindler; C. R. Kannewurf; W. Y. Leung; M. Benz; E. LeGoff; M. G. Kanatzidis

doi:10.1016/0379-6779(91)91500-A

Intercalation of polyfuran in FeOCl.

C. G. Wu, H. O. Marcy, D. C. DeGroot, J. L. Schindler, C. R. Kannewurf, W. Y. Leung, M. Benz, E. LeGoff, M. G. Kanatzidis

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

23 引文斯高帕斯（Scopus）

摘要

The intercalation of polyfuran, by in-situ intercalative oxidative polymerization of terfuran in FeOCl is reported. The intercalation reaction proceeds to completion in methanol in a sealed tube at 100 °C. The resulting compound, polyfuran/FeOCl (I), is crystalline. An interlayer expansion of ≈7.7 A ̊ is observed upon intercalation. The formation of polyfuran in the interlayer space of the host material was confirmed by FTIR spectroscopy and by isolation of the polymers from the host. Tetrafuran could not be intercalated completely under the conditions employed. Electrical conductivity and thermoelectric power data from pressed pellets of (I) are reported and the results are compared with other FeOCl intercalated polymers. X-ray diffraction, magnetic, infrared spectroscopic and scanning and transmission electron microscopic characterization of (I) are reported.

原文	???core.languages.en_GB???
頁（從 - 到）	797-803
頁數	7
期刊	Synthetic Metals
卷	41
發行號	3
DOIs	https://doi.org/10.1016/0379-6779(91)91500-A
出版狀態	已出版 - 6 5月 1991

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10.1016/0379-6779(91)91500-A

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@article{35aafae351fa408887eb2aee493594d2,

title = "Intercalation of polyfuran in FeOCl.",

abstract = "The intercalation of polyfuran, by in-situ intercalative oxidative polymerization of terfuran in FeOCl is reported. The intercalation reaction proceeds to completion in methanol in a sealed tube at 100 °C. The resulting compound, polyfuran/FeOCl (I), is crystalline. An interlayer expansion of ≈7.7 A ̊ is observed upon intercalation. The formation of polyfuran in the interlayer space of the host material was confirmed by FTIR spectroscopy and by isolation of the polymers from the host. Tetrafuran could not be intercalated completely under the conditions employed. Electrical conductivity and thermoelectric power data from pressed pellets of (I) are reported and the results are compared with other FeOCl intercalated polymers. X-ray diffraction, magnetic, infrared spectroscopic and scanning and transmission electron microscopic characterization of (I) are reported.",

author = "Wu, {C. G.} and Marcy, {H. O.} and DeGroot, {D. C.} and Schindler, {J. L.} and Kannewurf, {C. R.} and Leung, {W. Y.} and M. Benz and E. LeGoff and Kanatzidis, {M. G.}",

note = "Funding Information: Acknowledgement. Financial support from the National Science Foundation (grant DMR-8917805 to MGK) is gratefully acknowledged. At Northwestern University support was provided by ONR; this work made use of Central Facilities supported by NSF through the Materials Research Center.",

year = "1991",

month = may,

day = "6",

doi = "10.1016/0379-6779(91)91500-A",

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volume = "41",

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TY - JOUR

T1 - Intercalation of polyfuran in FeOCl.

AU - Wu, C. G.

AU - Marcy, H. O.

AU - DeGroot, D. C.

AU - Schindler, J. L.

AU - Kannewurf, C. R.

AU - Leung, W. Y.

AU - Benz, M.

AU - LeGoff, E.

AU - Kanatzidis, M. G.

N1 - Funding Information: Acknowledgement. Financial support from the National Science Foundation (grant DMR-8917805 to MGK) is gratefully acknowledged. At Northwestern University support was provided by ONR; this work made use of Central Facilities supported by NSF through the Materials Research Center.

PY - 1991/5/6

Y1 - 1991/5/6

N2 - The intercalation of polyfuran, by in-situ intercalative oxidative polymerization of terfuran in FeOCl is reported. The intercalation reaction proceeds to completion in methanol in a sealed tube at 100 °C. The resulting compound, polyfuran/FeOCl (I), is crystalline. An interlayer expansion of ≈7.7 A ̊ is observed upon intercalation. The formation of polyfuran in the interlayer space of the host material was confirmed by FTIR spectroscopy and by isolation of the polymers from the host. Tetrafuran could not be intercalated completely under the conditions employed. Electrical conductivity and thermoelectric power data from pressed pellets of (I) are reported and the results are compared with other FeOCl intercalated polymers. X-ray diffraction, magnetic, infrared spectroscopic and scanning and transmission electron microscopic characterization of (I) are reported.

AB - The intercalation of polyfuran, by in-situ intercalative oxidative polymerization of terfuran in FeOCl is reported. The intercalation reaction proceeds to completion in methanol in a sealed tube at 100 °C. The resulting compound, polyfuran/FeOCl (I), is crystalline. An interlayer expansion of ≈7.7 A ̊ is observed upon intercalation. The formation of polyfuran in the interlayer space of the host material was confirmed by FTIR spectroscopy and by isolation of the polymers from the host. Tetrafuran could not be intercalated completely under the conditions employed. Electrical conductivity and thermoelectric power data from pressed pellets of (I) are reported and the results are compared with other FeOCl intercalated polymers. X-ray diffraction, magnetic, infrared spectroscopic and scanning and transmission electron microscopic characterization of (I) are reported.

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U2 - 10.1016/0379-6779(91)91500-A

DO - 10.1016/0379-6779(91)91500-A

M3 - 期刊論文

AN - SCOPUS:0026417943

VL - 41

SP - 797

EP - 803

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 3

ER -

Intercalation of polyfuran in FeOCl.

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