Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure

Stephen C. Foster; Yen Chu Hsu; Cristino P. Damo; Xianming Liu; Chung Yi Kung; Terry A. Miller

doi:10.1021/j100284a011

Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure

Stephen C. Foster, Yen Chu Hsu, Cristino P. Damo, Xianming Liu, Chung Yi Kung, Terry A. Miller

物理學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

42 引文斯高帕斯（Scopus）

摘要

Laser excitation spectra of several alkoxy radicals including methoxy, ethoxy, vinoxy, and isopropoxy have been recorded at low temperature in a supersonic free jet expansion. These spectra in all cases show well-resolved rotational structure. These structures are used to determine the symmetry of the two electronic states involved in the transitions. The symmetries so determined are rationalized in terms of simple molecular orbital theory.

原文	???core.languages.en_GB???
頁（從 - 到）	6766-6769
頁數	4
期刊	Journal of Physical Chemistry
卷	90
發行號	26
DOIs	https://doi.org/10.1021/j100284a011
出版狀態	已出版 - 1986

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10.1021/j100284a011

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AU - Damo, Cristino P.

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AU - Kung, Chung Yi

AU - Miller, Terry A.

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AB - Laser excitation spectra of several alkoxy radicals including methoxy, ethoxy, vinoxy, and isopropoxy have been recorded at low temperature in a supersonic free jet expansion. These spectra in all cases show well-resolved rotational structure. These structures are used to determine the symmetry of the two electronic states involved in the transitions. The symmetries so determined are rationalized in terms of simple molecular orbital theory.

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Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure

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