Imbibition dynamics and steady flows in graphene nanochannels with sparse geometric and chemical defects

Yi Ting Cheng, Hsin Yu Chang, Heng Kwong Tsao, Yu Jane Sheng

研究成果: 雜誌貢獻期刊論文同行評審

5 引文 斯高帕斯(Scopus)

摘要

Geometric and chemical defects are frequently found or created on smooth graphene for applications of nanofluidics. In this work, imbibition dynamics and steady flows of water in graphene nanochannels with sparse defects are explored by molecular dynamics. The water contact angle is raised slightly by geometric defects (hole and protrusion) but lowered significantly by chemical defects (hydroxyl and epoxide groups). In steady flows, the mean velocity and slip length are always reduced by sparse defects and the effect of chemical defects is more significant than that of geometric defects. Moreover, it is interesting to find that the velocity profile is plug-like for geometric defects but becomes parabolic for chemical defects, regardless of the slip length. Sparse defects on graphene nanoslits also affect the imbibition dynamics remarkably, which generally follows Washburn's equation with the slip length. For chemical defects, surface friction (slip length) dominates over the driving force associated with surface wettability (contact angle). Nonetheless, for protrusion defects, the stick-slip behavior caused by contact line pinning and thermal fluctuations can be observed. Our new and novel findings indicate that the defect nature is crucial in nanoscale flows and imbibition processes, which the conventional hydrodynamic theory fails to depict.

原文???core.languages.en_GB???
文章編號112003
期刊Physics of Fluids
34
發行號11
DOIs
出版狀態已出版 - 1 11月 2022

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