Heterogenization of [Cu(NCCH3)6][B(C 6F5)4]2 and its application in catalytic olefin aziridination

Ayyamperumal Sakthivel, Ahmed K. Hijazi, Marianne Hanzlik, Anthony S.T. Chiang, Fritz E. Kühn

研究成果: 雜誌貢獻期刊論文同行評審

26 引文 斯高帕斯(Scopus)

摘要

[Cu(NCCH3)6][B(C6F5) 4]2 can be heterogenized by ion exchange on NaAlMCM-41 and NaAlMCM-48. In the latter case, the observed loading is twice as high as in the first case. [Cu(NCCH3)6][B(C6F 5)4]2 is applicable both in homogeneous and heterogeneous media for the aziridination of olefins at 30°C. Good yields are observed for non bulky olefins, olefins with bulkier substituents lead to lower yields. [Cu(NCCH3)6][B(C6F 5)4]2 grafted on mesoporous surfaces (as heterogeneous catalyst) is stable and recyclable for several catalytic runs with only slight decrease in catalytic activity.

原文???core.languages.en_GB???
頁(從 - 到)161-167
頁數7
期刊Applied Catalysis A: General
294
發行號2
DOIs
出版狀態已出版 - 10 10月 2005

指紋

深入研究「Heterogenization of [Cu(NCCH3)6][B(C 6F5)4]2 and its application in catalytic olefin aziridination」主題。共同形成了獨特的指紋。

引用此