摘要
[Cu(NCCH3)6][B(C6F5) 4]2 can be heterogenized by ion exchange on NaAlMCM-41 and NaAlMCM-48. In the latter case, the observed loading is twice as high as in the first case. [Cu(NCCH3)6][B(C6F 5)4]2 is applicable both in homogeneous and heterogeneous media for the aziridination of olefins at 30°C. Good yields are observed for non bulky olefins, olefins with bulkier substituents lead to lower yields. [Cu(NCCH3)6][B(C6F 5)4]2 grafted on mesoporous surfaces (as heterogeneous catalyst) is stable and recyclable for several catalytic runs with only slight decrease in catalytic activity.
原文 | ???core.languages.en_GB??? |
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頁(從 - 到) | 161-167 |
頁數 | 7 |
期刊 | Applied Catalysis A: General |
卷 | 294 |
發行號 | 2 |
DOIs | |
出版狀態 | 已出版 - 10 10月 2005 |