@article{4cf73019ec654805ba2d405353d9946c,
title = "Heterogenization of chiral molybdenum(VI) dioxo complexes on mesoporous materials and their application in catalysis",
abstract = "Optically active molybdenum(VI) dioxo complexes bearing hydrosalen derivatives as ligands were synthesized, grafted on the surface of MCM-41 and MCM-48 and examined as catalysts for asymmetric epoxidation. In case of cis-β-methylstyrene and trans-β-methylstyrene moderate enantiomeric excesses of up to 31\% can be reached when the reaction is carried out at room temperature. The catalysts can also be applied for non-chiral oxidation reactions.",
keywords = "Catalysis, Chirality, Epoxidation, Mesoporous materials, Molybdenum",
author = "Ayyamperumal Sakthivel and Jin Zhao and Gabriele Raudaschl-Sieber and Marianne Hanzlik and Chiang, \{Anthony S.T.\} and K{\"u}hn, \{Fritz E.\}",
note = "Funding Information: A.S. is grateful to the Alexander von Humboldt Foundation for a postdoctoral research fellowship. J.Z. thanks the Deutscher Akademischer Austauschdienst (DAAD) for a Ph D grant.",
year = "2005",
month = mar,
day = "18",
doi = "10.1016/j.apcata.2004.11.035",
language = "???core.languages.en\_GB???",
volume = "281",
pages = "267--273",
journal = "Applied Catalysis A: General",
issn = "0926-860X",
number = "1-2",
}