Heterogenization of chiral molybdenum(VI) dioxo complexes on mesoporous materials and their application in catalysis

Ayyamperumal Sakthivel, Jin Zhao, Gabriele Raudaschl-Sieber, Marianne Hanzlik, Anthony S.T. Chiang, Fritz E. Kühn

研究成果: 雜誌貢獻期刊論文同行評審

68 引文 斯高帕斯(Scopus)

摘要

Optically active molybdenum(VI) dioxo complexes bearing hydrosalen derivatives as ligands were synthesized, grafted on the surface of MCM-41 and MCM-48 and examined as catalysts for asymmetric epoxidation. In case of cis-β-methylstyrene and trans-β-methylstyrene moderate enantiomeric excesses of up to 31% can be reached when the reaction is carried out at room temperature. The catalysts can also be applied for non-chiral oxidation reactions.

原文???core.languages.en_GB???
頁(從 - 到)267-273
頁數7
期刊Applied Catalysis A: General
281
發行號1-2
DOIs
出版狀態已出版 - 18 3月 2005

指紋

深入研究「Heterogenization of chiral molybdenum(VI) dioxo complexes on mesoporous materials and their application in catalysis」主題。共同形成了獨特的指紋。

引用此