Green and rapid synthesis of zirconium metal-organic frameworks: Via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

Yi Hao Huang, Wei Shang Lo, Yun Wei Kuo, Wen Jin Chen, Chia Her Lin, Fa Kuen Shieh

研究成果: 雜誌貢獻期刊論文同行評審

58 引文 斯高帕斯(Scopus)

摘要

A UiO-66 analog was synthesized in 100 s using water-assisted grinding. The linker solubility suggested that tetrafluorobenzene-1,4-dicarboxylic acid was the best linker. Zr-metal-organic framework nanocrystals displayed good topologies and hydrophobicities, and high water/thermal stabilities. The less amorphous complex led to higher porosities and pore volumes with a 60 min grinding time.

原文???core.languages.en_GB???
頁(從 - 到)5818-5821
頁數4
期刊Chemical Communications
53
發行號43
DOIs
出版狀態已出版 - 2017

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