TY - JOUR
T1 - Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates
AU - Sakthivel, Ayyamperumal
AU - Pedro, Filipe M.
AU - Chiang, Anthony S.T.
AU - Kühn, Fritz E.
PY - 2006/11/15
Y1 - 2006/11/15
N2 - Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.
AB - Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.
UR - http://www.scopus.com/inward/record.url?scp=85034342973&partnerID=8YFLogxK
U2 - 10.1039/b611550k
DO - 10.1039/b611550k
M3 - 期刊論文
AN - SCOPUS:33845986745
SN - 0300-9246
SP - 320
EP - 326
JO - Journal of the Chemical Society - Dalton Transactions
JF - Journal of the Chemical Society - Dalton Transactions
IS - 3
ER -