Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

Ayyamperumal Sakthivel, Filipe M. Pedro, Anthony S.T. Chiang, Fritz E. Kühn

研究成果: 雜誌貢獻期刊論文同行評審

10 引文 斯高帕斯(Scopus)

摘要

Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.

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頁(從 - 到)320-326
頁數7
期刊Journal of the Chemical Society - Dalton Transactions
發行號3
DOIs
出版狀態已出版 - 15 11月 2006

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