Grafting of η5-Cp(COOMe)MoCl(CO)3 on the surface of mesoporous MCM-41 and MCM-48 materials

Ayyamperumal Sakthivel, Marta Abrantes, Anthony S.T. Chiang, Fritz E. Kühn

研究成果: 雜誌貢獻期刊論文同行評審

30 引文 斯高帕斯(Scopus)

摘要

η5-Cp(COOMe)MoCl(CO)3 is grafted on the surface of mesoporous MCM-41 and MCM-48 materials through available silanol groups. The structural intactness of the supporting materials is confirmed by powder XRD and N2 adsorption analysis. The presence of the Mo complex on the surface is confirmed by FT-IR and elemental analysis. The catalysts are successfully applied for cyclooctene epoxidation.

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頁(從 - 到)1007-1011
頁數5
期刊Journal of Organometallic Chemistry
691
發行號5
DOIs
出版狀態已出版 - 15 2月 2006

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