Gilman-type versus Lipshutz-type reagents: Competition in lithiocuprate chemistry

Joanna Haywood, James V. Morey, E. H.Andrew Wheatley, Ching Yuan Liu, Shuji Yasuike, Jyoji Kurita, Masanobu Uchiyama, Paul R. Raithby

研究成果: 雜誌貢獻期刊論文同行評審

29 引文 斯高帕斯(Scopus)

摘要

CuCN reacts with RLi and TMPLi (TMP-2,2,6,6-tetramethylpiperidide) to give Gilman-type cuprates R(TMP)CuLi•nL (R = Ph,n = 3,L = THF 2; R = Me,n = 1,L = TMEDA 3). 3 and 3. LiCN have been tested in directed ortho cupration with data suggesting enhanced efficiency for Lipshutz-type 3. LiCN; competition between Lipshutz- and Gilman-type formulations is rationalized by DFT methods.

原文???core.languages.en_GB???
頁(從 - 到)38-41
頁數4
期刊Organometallics
28
發行號1
DOIs
出版狀態已出版 - 12 1月 2009

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