Ferromagnetic insulating state in tensile-strained LaCoO 3 thin films from LDA + U calculations

Han Hsu, Peter Blaha, Renata M. Wentzcovitch

研究成果: 雜誌貢獻期刊論文同行評審

62 引文 斯高帕斯(Scopus)

摘要

With local density approximation+Hubbard U (LDA+U) calculations, we show that the ferromagnetic (FM) insulating state observed in tensile-strained LaCoO 3 epitaxial thin films is most likely a mixture of low-spin (LS) and high-spin (HS) Co, namely, a HS/LS mixture state. Compared with other FM states, including the intermediate-spin (IS) state (metallic within LDA+U), which consists of IS Co only, and the insulating IS/LS mixture state, the HS/LS state is the most favorable one. The FM order in the HS/LS state is stabilized via the superexchange interactions between adjacent LS and HS Co. We also show that the Co spin state can be identified by measuring the electric field gradient at the Co nucleus via nuclear magnetic resonance spectroscopy.

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文章編號140404
期刊Physical Review B - Condensed Matter and Materials Physics
85
發行號14
DOIs
出版狀態已出版 - 11 4月 2012

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