Enhancement of power conversion efficiency of TiO2-based dye-sensitized solar cells on various acid treatment

Pedaballi Sireesha, Wei Gang Sun, Chaochin Su, Sasipriya Kathirvel, Woranan Lekphet, Suri Babu Akula, Wen Ren Li

研究成果: 雜誌貢獻期刊論文同行評審

3 引文 斯高帕斯(Scopus)

摘要

The surface modification of the TiO2 photoelectrode film is one of the promising ways to improve the photovoltaic performance of dye-sensitized solar cell (DSSC). In this work for the acid treatment of TiO2 powder, fluorine containing compounds such as trifluoroacetic acid was carried out to enhance the properties of photoanode. In order to investigate the effect of trifluoroacetyl group, the TiO2 nanopowders were also treated with different acids such as acetic acid, nitric acid, hydrochloric acid, and sulfuric acid and their properties were compared. The TiO2 powders treated with both acetic acid and TFA have possessed smooth surface morphologies as well as enhanced particle dispersions with reduced particle sizes. Photoelectrodes prepared for these two kinds of TiO2 powders accommodated high amounts of dye loading and exhibited excellent light transmittance (wavelength region of 400-600 nm). Electrochemical impedance spectroscopy analysis showed the smallest radius of the semicircle which indicates the enhanced rate of electron transport for the cell based photoelectrode with trifluoroacetic acid treated TiO2 powder. The solar cell from the untreated TiO2 film showed the power conversion efficiency of 8.86% and the highest efficiency of 9.51% was achieved by the cell fabricated from trifluoroacetic acid treated TiO2 film.

原文???core.languages.en_GB???
頁(從 - 到)354-362
頁數9
期刊Journal of Nanoscience and Nanotechnology
17
發行號1
DOIs
出版狀態已出版 - 2017

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