Electron transfer reactions of metal carbonyl anions

Jim D. Atwood, M. Shauna Corraine-Pandolfino, Y. Yueqian, Z. Zhen, William S. Striejewske, C. K. Lai, Ping Wang

研究成果: 雜誌貢獻期刊論文同行評審

7 引文 斯高帕斯(Scopus)

摘要

Metal carbonyl anions exhibit one- and two-electron reactions. The two-electron processes involving transfer of groups (hydrogen, alkyl, and halogen) between metal centers are related to the nucleophilicity. The one-electron processes are primarily outer-sphere electron transfer for the metal carbonyl anions. These reactions are observed in the presence of oxidants such as coordination complexes, pyridinium salts, metal carbonyl dimers and metal carbonyl clusters. However, in contrast to organic reactions, the metal carbonyl anions may undergo inner-sphere electron transfer. Reactions of metal carbonyl anions of low nucleophilicity with metal carbonyl cations or halides are best interpreted as inner-sphere, one-electron transfer.

原文???core.languages.en_GB???
頁(從 - 到)65-78
頁數14
期刊Journal of Coordination Chemistry
32
發行號1-3
DOIs
出版狀態已出版 - 1 6月 1994

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