ELECTRON-TRANSFER KINETICS OF REDOX CENTERS ANCHORED TO METAL SURFACES: WEAK- VERSUS STRONG-OVERLAP REACTION PATHWAYS.

S. W. Barr; K. L. Guyer; T. T.T. Li; H. Y. Liu; M. J. Weaver

ELECTRON-TRANSFER KINETICS OF REDOX CENTERS ANCHORED TO METAL SURFACES: WEAK- VERSUS STRONG-OVERLAP REACTION PATHWAYS.

S. W. Barr, K. L. Guyer, T. T.T. Li, H. Y. Liu, M. J. Weaver

機械工程學系

研究成果: 雜誌貢獻 › 會議論文 › 同行評審

摘要

Unimolecular rate constants k//e//t are presented for the one-electron electroreduction of various Co**I**I**I(NH//3)//5X complexes bound to mercury, platinum, and gold surfaces via either small inorganic or extended organic ligands X. These 'surface intramolecular' rate parameters are compared with estimates of k//e//t for outer-sphere pathways obtained from homogeneous rate data in order to ascertain the consequences of reactant-surface binding upon the electron-transfer energetics.

原文	???core.languages.en_GB???
頁（從 - 到）	425-440
頁數	16
期刊	Proceedings - The Electrochemical Society
卷	84-12
出版狀態	已出版 - 1984

引用此

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abstract = "Unimolecular rate constants k//e//t are presented for the one-electron electroreduction of various Co**I**I**I(NH//3)//5X complexes bound to mercury, platinum, and gold surfaces via either small inorganic or extended organic ligands X. These 'surface intramolecular' rate parameters are compared with estimates of k//e//t for outer-sphere pathways obtained from homogeneous rate data in order to ascertain the consequences of reactant-surface binding upon the electron-transfer energetics.",

author = "Barr, {S. W.} and Guyer, {K. L.} and Li, {T. T.T.} and Liu, {H. Y.} and Weaver, {M. J.}",

year = "1984",

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volume = "84-12",

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journal = "Proceedings - The Electrochemical Society",

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TY - JOUR

T1 - ELECTRON-TRANSFER KINETICS OF REDOX CENTERS ANCHORED TO METAL SURFACES

T2 - WEAK- VERSUS STRONG-OVERLAP REACTION PATHWAYS.

AU - Barr, S. W.

AU - Guyer, K. L.

AU - Li, T. T.T.

AU - Liu, H. Y.

AU - Weaver, M. J.

PY - 1984

Y1 - 1984

N2 - Unimolecular rate constants k//e//t are presented for the one-electron electroreduction of various Co**I**I**I(NH//3)//5X complexes bound to mercury, platinum, and gold surfaces via either small inorganic or extended organic ligands X. These 'surface intramolecular' rate parameters are compared with estimates of k//e//t for outer-sphere pathways obtained from homogeneous rate data in order to ascertain the consequences of reactant-surface binding upon the electron-transfer energetics.

AB - Unimolecular rate constants k//e//t are presented for the one-electron electroreduction of various Co**I**I**I(NH//3)//5X complexes bound to mercury, platinum, and gold surfaces via either small inorganic or extended organic ligands X. These 'surface intramolecular' rate parameters are compared with estimates of k//e//t for outer-sphere pathways obtained from homogeneous rate data in order to ascertain the consequences of reactant-surface binding upon the electron-transfer energetics.

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M3 - 會議論文

AN - SCOPUS:0021584879

SN - 0161-6374

VL - 84-12

SP - 425

EP - 440

JO - Proceedings - The Electrochemical Society

JF - Proceedings - The Electrochemical Society

ER -

ELECTRON-TRANSFER KINETICS OF REDOX CENTERS ANCHORED TO METAL SURFACES: WEAK- VERSUS STRONG-OVERLAP REACTION PATHWAYS.

摘要

指紋

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