Electrochemistry of C60 films: Quartz crystal microbalance and mass spectrometric studies

Feimeng Zhou, Shueh Lin Yau, Christophe Jehoulet, David A. Laude, Ziqiang Guan, Allen J. Bard

研究成果: 雜誌貢獻期刊論文同行評審

57 引文 斯高帕斯(Scopus)

摘要

The incorporation of tetra-n-butylammonium (TBA+) upon electroreduction of films of C60 on an electrode in MeCN solutions was studied by electrochemical quartz crystal microbalance (EQCM) and laser desorption mass spectrometry (LDMS) methods. EQCM allowed estimation of the extent of dissolution of the films upon reduction to the C60- and C602- forms and the increase in mass caused by incorporation of TBA+. LDMS analysis also indicated the presence of TBA+ after reduction. Both methods suggested that TBA+ remains in the lattice after reoxidation of the reduced forms to C60, indicating a new type of "ionic charge trapping" in these films.

原文???core.languages.en_GB???
頁(從 - 到)4160-4162
頁數3
期刊Journal of Physical Chemistry
96
發行號11
DOIs
出版狀態已出版 - 1992

指紋

深入研究「Electrochemistry of C60 films: Quartz crystal microbalance and mass spectrometric studies」主題。共同形成了獨特的指紋。

引用此