Electrochemical fluorination of methanedisulfonyl fluoride

F. W. Klink; D. J. Wasser; C. C. Liu

doi:10.1016/S0022-1139(00)80508-4

Electrochemical fluorination of methanedisulfonyl fluoride

F. W. Klink, D. J. Wasser, C. C. Liu

材料科學與工程研究所

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

10 引文斯高帕斯（Scopus）

摘要

The electrochemical fluorination of methanedisulfonyl fluoride in anhydrous hydrogen fluoride to produce difluoromethanedisulfonyl fluoride, a precursor of difluoromethane disulfonic acid, was investigated. This study was carried out in a microprocessor-aided modified Simons' reactor system at constant anodic potential using a Cu/CuF₂ reference electrode. Product yields of 75-82%, current efftciencies in excess of 66%, and electrical energy efficiencies of at least 33% were obtained for the electrochemical fluorination step. Experimental results of this investigation are presented and discussed.

原文	???core.languages.en_GB???
頁（從 - 到）	89-101
頁數	13
期刊	Journal of Fluorine Chemistry
卷	32
發行號	1
DOIs	https://doi.org/10.1016/S0022-1139(00)80508-4
出版狀態	已出版 - 6月 1986

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10.1016/S0022-1139(00)80508-4

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title = "Electrochemical fluorination of methanedisulfonyl fluoride",

abstract = "The electrochemical fluorination of methanedisulfonyl fluoride in anhydrous hydrogen fluoride to produce difluoromethanedisulfonyl fluoride, a precursor of difluoromethane disulfonic acid, was investigated. This study was carried out in a microprocessor-aided modified Simons' reactor system at constant anodic potential using a Cu/CuF2 reference electrode. Product yields of 75-82\%, current efftciencies in excess of 66\%, and electrical energy efficiencies of at least 33\% were obtained for the electrochemical fluorination step. Experimental results of this investigation are presented and discussed.",

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T1 - Electrochemical fluorination of methanedisulfonyl fluoride

AU - Klink, F. W.

AU - Wasser, D. J.

AU - Liu, C. C.

PY - 1986/6

Y1 - 1986/6

N2 - The electrochemical fluorination of methanedisulfonyl fluoride in anhydrous hydrogen fluoride to produce difluoromethanedisulfonyl fluoride, a precursor of difluoromethane disulfonic acid, was investigated. This study was carried out in a microprocessor-aided modified Simons' reactor system at constant anodic potential using a Cu/CuF2 reference electrode. Product yields of 75-82%, current efftciencies in excess of 66%, and electrical energy efficiencies of at least 33% were obtained for the electrochemical fluorination step. Experimental results of this investigation are presented and discussed.

AB - The electrochemical fluorination of methanedisulfonyl fluoride in anhydrous hydrogen fluoride to produce difluoromethanedisulfonyl fluoride, a precursor of difluoromethane disulfonic acid, was investigated. This study was carried out in a microprocessor-aided modified Simons' reactor system at constant anodic potential using a Cu/CuF2 reference electrode. Product yields of 75-82%, current efftciencies in excess of 66%, and electrical energy efficiencies of at least 33% were obtained for the electrochemical fluorination step. Experimental results of this investigation are presented and discussed.

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U2 - 10.1016/S0022-1139(00)80508-4

DO - 10.1016/S0022-1139(00)80508-4

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SN - 0022-1139

VL - 32

SP - 89

EP - 101

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 1

ER -

Electrochemical fluorination of methanedisulfonyl fluoride

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