Electrochemical fluorination of methanedisulfonyl fluoride

F. W. Klink, D. J. Wasser, C. C. Liu

研究成果: 雜誌貢獻期刊論文同行評審

9 引文 斯高帕斯(Scopus)

摘要

The electrochemical fluorination of methanedisulfonyl fluoride in anhydrous hydrogen fluoride to produce difluoromethanedisulfonyl fluoride, a precursor of difluoromethane disulfonic acid, was investigated. This study was carried out in a microprocessor-aided modified Simons' reactor system at constant anodic potential using a Cu/CuF2 reference electrode. Product yields of 75-82%, current efftciencies in excess of 66%, and electrical energy efficiencies of at least 33% were obtained for the electrochemical fluorination step. Experimental results of this investigation are presented and discussed.

原文???core.languages.en_GB???
頁(從 - 到)89-101
頁數13
期刊Journal of Fluorine Chemistry
32
發行號1
DOIs
出版狀態已出版 - 6月 1986

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