Electrochemical characterization of a branched oligomer as a high-temperature and long-cycle-life additive for lithium-ion batteries

Yu Han Li; Meng Lun Lee; Fu Ming Wang; Chang Rung Yang; Peter P.J. Chu; Jing Pin Pan

doi:10.1016/j.electacta.2012.08.062

Electrochemical characterization of a branched oligomer as a high-temperature and long-cycle-life additive for lithium-ion batteries

Yu Han Li, Meng Lun Lee, Fu Ming Wang, Chang Rung Yang, Peter P.J. Chu, Jing Pin Pan

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

6 引文斯高帕斯（Scopus）

摘要

We selected a maleimide-based branched oligomer (BO) as a high-temperature and long-cycle-life additive and studied the influence of different amounts of the BO additive on the electrochemical performance of lithium-ion batteries. The electrochemical performances of the additive-containing electrolytes in combination with a cell composed of a LiCoO₂ cathode and a mesocarbon microbead (MCMB) anode were tested in coin cells. The cyclic voltammetry (CV) results showed that the oxidation potential of the BO is about 1.9 V versus Li/Li+ and a thin film grown on the surface of the cathode. In the present work, 1.0 wt.% BO in 1.0 M LiPF₆/EC:DEC (4:6 by vol.%) electrolyte was the optimal condition for the improvement of the cycle ability of battery, especially, at high temperature (55 °C) condition.

原文	???core.languages.en_GB???
頁（從 - 到）	72-77
頁數	6
期刊	Electrochimica Acta
卷	85
DOIs	https://doi.org/10.1016/j.electacta.2012.08.062
出版狀態	已出版 - 15 12月 2012

UN SDG

此研究成果有助於以下永續發展目標

存取文件

10.1016/j.electacta.2012.08.062

引用此

@article{69bca2e1937644ffa3bef34aed727ea5,

title = "Electrochemical characterization of a branched oligomer as a high-temperature and long-cycle-life additive for lithium-ion batteries",

abstract = "We selected a maleimide-based branched oligomer (BO) as a high-temperature and long-cycle-life additive and studied the influence of different amounts of the BO additive on the electrochemical performance of lithium-ion batteries. The electrochemical performances of the additive-containing electrolytes in combination with a cell composed of a LiCoO2 cathode and a mesocarbon microbead (MCMB) anode were tested in coin cells. The cyclic voltammetry (CV) results showed that the oxidation potential of the BO is about 1.9 V versus Li/Li+ and a thin film grown on the surface of the cathode. In the present work, 1.0 wt.% BO in 1.0 M LiPF6/EC:DEC (4:6 by vol.%) electrolyte was the optimal condition for the improvement of the cycle ability of battery, especially, at high temperature (55 °C) condition.",

keywords = "Branched oligomer, High temperature, Long cycle life",

author = "Li, {Yu Han} and Lee, {Meng Lun} and Wang, {Fu Ming} and Yang, {Chang Rung} and Chu, {Peter P.J.} and Pan, {Jing Pin}",

note = "Funding Information: The authors would like to thank the National Science Council for financially supporting this research. The technical assistance of the National Central University and Materials and Chemical Research Laboratories of the Industrial Technology Research Institute (Taiwan) is appreciated.",

year = "2012",

month = dec,

day = "15",

doi = "10.1016/j.electacta.2012.08.062",

language = "???core.languages.en_GB???",

volume = "85",

pages = "72--77",

journal = "Electrochimica Acta",

issn = "0013-4686",

}

TY - JOUR

T1 - Electrochemical characterization of a branched oligomer as a high-temperature and long-cycle-life additive for lithium-ion batteries

AU - Li, Yu Han

AU - Lee, Meng Lun

AU - Wang, Fu Ming

AU - Yang, Chang Rung

AU - Chu, Peter P.J.

AU - Pan, Jing Pin

N1 - Funding Information: The authors would like to thank the National Science Council for financially supporting this research. The technical assistance of the National Central University and Materials and Chemical Research Laboratories of the Industrial Technology Research Institute (Taiwan) is appreciated.

PY - 2012/12/15

Y1 - 2012/12/15

N2 - We selected a maleimide-based branched oligomer (BO) as a high-temperature and long-cycle-life additive and studied the influence of different amounts of the BO additive on the electrochemical performance of lithium-ion batteries. The electrochemical performances of the additive-containing electrolytes in combination with a cell composed of a LiCoO2 cathode and a mesocarbon microbead (MCMB) anode were tested in coin cells. The cyclic voltammetry (CV) results showed that the oxidation potential of the BO is about 1.9 V versus Li/Li+ and a thin film grown on the surface of the cathode. In the present work, 1.0 wt.% BO in 1.0 M LiPF6/EC:DEC (4:6 by vol.%) electrolyte was the optimal condition for the improvement of the cycle ability of battery, especially, at high temperature (55 °C) condition.

AB - We selected a maleimide-based branched oligomer (BO) as a high-temperature and long-cycle-life additive and studied the influence of different amounts of the BO additive on the electrochemical performance of lithium-ion batteries. The electrochemical performances of the additive-containing electrolytes in combination with a cell composed of a LiCoO2 cathode and a mesocarbon microbead (MCMB) anode were tested in coin cells. The cyclic voltammetry (CV) results showed that the oxidation potential of the BO is about 1.9 V versus Li/Li+ and a thin film grown on the surface of the cathode. In the present work, 1.0 wt.% BO in 1.0 M LiPF6/EC:DEC (4:6 by vol.%) electrolyte was the optimal condition for the improvement of the cycle ability of battery, especially, at high temperature (55 °C) condition.

KW - Branched oligomer

KW - High temperature

KW - Long cycle life

UR - http://www.scopus.com/inward/record.url?scp=84870461281&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2012.08.062

DO - 10.1016/j.electacta.2012.08.062

M3 - 期刊論文

AN - SCOPUS:84870461281

SN - 0013-4686

VL - 85

SP - 72

EP - 77

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

Electrochemical characterization of a branched oligomer as a high-temperature and long-cycle-life additive for lithium-ion batteries

摘要

UN SDG

存取文件

指紋

引用此