Direct Acetoxylation of Arenes

Thi Anh Hong Nguyen, Duen Ren Hou

研究成果: 雜誌貢獻期刊論文同行評審

1 引文 斯高帕斯(Scopus)

摘要

Acetoxylation of arenes is an important reaction and an unmet need in chemistry. We report a metal-free, direct acetoxylation reaction using sodium nitrate under an anhydrous environment of trifluoroacetic acid, acetic acid, and acetic anhydride. Arenes (31 examples), with oxidation potentials (Eox, in V vs SCE) lower than benzene (2.48 V), were acetoxylated with good yields and regioselectivity. A stepwise, single electron-transfer mechanism is proposed.

原文???core.languages.en_GB???
頁(從 - 到)8127-8131
頁數5
期刊Organic Letters
23
發行號21
DOIs
出版狀態已出版 - 5 11月 2021

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