摘要
A study was conducted on the density fluctuation of counterions within aqueou droplets containing no macroions by Monte Carlo simulations. In terms of mean-square dipole moment, the fluctuation grows and becomes saturated as the counterin concentration was increased. As such, the mean-square dipole was found to be proportional to the volume of the microdroplet and was much greater than that induced by particle fluctuations alone, which was estimated from the mean-field theory.
原文 | ???core.languages.en_GB??? |
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頁(從 - 到) | 6689-6696 |
頁數 | 8 |
期刊 | Journal of Chemical Physics |
卷 | 118 |
發行號 | 14 |
DOIs | |
出版狀態 | 已出版 - 8 4月 2003 |