Design, synthesis and characterization of polysiloxane and polyetherdiamine based comb-shaped hybrid solid polymer electrolytes for applications in electrochemical devices

Juti Rani Deka, Diganta Saikia, Gwo Wei Lou, Chien Hua Lin, Jason Fang, Yung Chin Yang, Hsien Ming Kao

研究成果: 雜誌貢獻期刊論文同行評審

15 引文 斯高帕斯(Scopus)

摘要

In this study, polysiloxane and polyetherdiamine based comb-shaped solid polymer electrolytes (SPEs) are developed by hydrosilylation and sol-gel reactions of polymethylhydrosiloxane, allyltriethoxysilane, bis(2-aminopropyl) polypropylene glycol-block-polyethylene glycol-block-polypropylene glycol and (3-glycidoxypropyl)trimethoxysilane followed by LiClO4 doping. The absence of residual Si‒H functionality in FTIR and 29Si CPMAS NMR spectra confirms the completion of hydrosilylation reaction. The formation of comb-shaped SPEs with silicate backbones is confirmed by 13C and 29Si solid-state NMR spectroscopy. The maximum ionic conductivity value of 5.8 × 10−4 S cm−1 is obtained for the SPE with [O]/[Li] ratio of 16 at 80 °C with electrochemical stability window reaching up to 4.8 V. The fabricated electrochromic device with the hybrid SPE of [O]/[Li] = 16 demonstrates good electrochromic contrast and optical density change values of 49.3% and 0.39, respectively, at wavelength of 550 nm. The results show that the present comb-shaped SPEs have potential to be used in various electrochemical devices.

原文???core.languages.en_GB???
頁(從 - 到)72-81
頁數10
期刊Materials Research Bulletin
109
DOIs
出版狀態已出版 - 1月 2019

指紋

深入研究「Design, synthesis and characterization of polysiloxane and polyetherdiamine based comb-shaped hybrid solid polymer electrolytes for applications in electrochemical devices」主題。共同形成了獨特的指紋。

引用此