Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

Jorge L. Martinez; Hsiu Jung Lin; Wei Tsung Lee; Maren Pink; Chun Hsing Chen; Xinfeng Gao; Diane A. Dickie; Jeremy M. Smith

doi:10.1021/jacs.7b08704

Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

Jorge L. Martinez, Hsiu Jung Lin, Wei Tsung Lee, Maren Pink, Chun Hsing Chen, Xinfeng Gao, Diane A. Dickie, Jeremy M. Smith

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

33 引文斯高帕斯（Scopus）

摘要

The new iron(IV) nitride complex PhB(ⁱPr₂Im)₃Fe≡N reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB(ⁱPr₂Im)₃Fe(CN)(N₂)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne ⁱPr₂N-C≡C-NⁱPr₂. The iron complex is in equilibrium with an N₂-free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C₆F₅)₃ provides the cyanoborane derivative.

原文	???core.languages.en_GB???
頁（從 - 到）	14037-14040
頁數	4
期刊	Journal of the American Chemical Society
卷	139
發行號	40
DOIs	https://doi.org/10.1021/jacs.7b08704
出版狀態	已出版 - 11 10月 2017

存取文件

10.1021/jacs.7b08704

引用此

@article{66a4d71005ae4e829b5c2f8605b24097,

title = "Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride",

abstract = "The new iron(IV) nitride complex PhB(iPr2Im)3Fe≡N reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB(iPr2Im)3Fe(CN)(N2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne iPr2N-C≡C-NiPr2. The iron complex is in equilibrium with an N2-free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C6F5)3 provides the cyanoborane derivative.",

author = "Martinez, {Jorge L.} and Lin, {Hsiu Jung} and Lee, {Wei Tsung} and Maren Pink and Chen, {Chun Hsing} and Xinfeng Gao and Dickie, {Diane A.} and Smith, {Jeremy M.}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = oct,

day = "11",

doi = "10.1021/jacs.7b08704",

language = "???core.languages.en_GB???",

volume = "139",

pages = "14037--14040",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

number = "40",

}

TY - JOUR

T1 - Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

AU - Martinez, Jorge L.

AU - Lin, Hsiu Jung

AU - Lee, Wei Tsung

AU - Pink, Maren

AU - Chen, Chun Hsing

AU - Gao, Xinfeng

AU - Dickie, Diane A.

AU - Smith, Jeremy M.

PY - 2017/10/11

Y1 - 2017/10/11

N2 - The new iron(IV) nitride complex PhB(iPr2Im)3Fe≡N reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB(iPr2Im)3Fe(CN)(N2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne iPr2N-C≡C-NiPr2. The iron complex is in equilibrium with an N2-free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C6F5)3 provides the cyanoborane derivative.

AB - The new iron(IV) nitride complex PhB(iPr2Im)3Fe≡N reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB(iPr2Im)3Fe(CN)(N2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne iPr2N-C≡C-NiPr2. The iron complex is in equilibrium with an N2-free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C6F5)3 provides the cyanoborane derivative.

UR - http://www.scopus.com/inward/record.url?scp=85031115404&partnerID=8YFLogxK

U2 - 10.1021/jacs.7b08704

DO - 10.1021/jacs.7b08704

M3 - 期刊論文

C2 - 28933864

AN - SCOPUS:85031115404

SN - 0002-7863

VL - 139

SP - 14037

EP - 14040

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 40

ER -

Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

摘要

存取文件

指紋

引用此